D8(C3V-STAR)-EPR THEORY AND THE OPTICAL MAGNETIC-PROPERTIES OF NI2+-CSMGCL3 | |
P. F. Wu; Q. Y. Dong; S. B. Zhao; H. S. Wang; K. W. Zhou | |
1992 | |
发表期刊 | Science in China Series a-Mathematics Physics Astronomy
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ISSN | 1001-6511 |
卷号 | 35期号:3页码:298-310 |
摘要 | The complete strong-field-matrices for d2,8(C3v*) ions are constructed within an O(h)- point-group representation. Based on the eigenvalues and eigenvectors of these matrices, a complete-configuration-mixing EPR theory is established for Ni2+ ions in CsMgX (X = Cl, Br,I) kind crystals, and accordingly, a uniform calculation is performed for the optical absorption spectrum, the zero-field-splitting and Zeeman splitting of the ground state, the EPR parameters D and g and the EPR conditions (B,h-nu) of Ni2+ impurity ions in a CsMgCl3 crystal. The results are in very good agreement with the experimental, thus a uniform theoretical interpretation is achieved for the optical and magnetic properties of Ni2+:CsMgCl3 for the first time. |
部门归属 | jishou univ,dept phys,jishou 416000,peoples r china. nanchong educ coll,dept phys,nanchung 637000,peoples r china. sichuan normal univ,dept chem,chengdu 610066,peoples r china. sichuan normal univ,dept phys,chengdu 610066,peoples r china. acad sinica,int ctr mat phys,shenyang,peoples r china. sichuan univ,dept phys,chengdu 610064,peoples r china.;wu, pf (reprint author), china ctr adv sci & technol,ctr theoret phys,world lab,beijing 100080,peoples r china |
关键词 | Complete Strong-field-matrix For D2 8(C3v-star) Complete-configuration-mixing Epr Theory Csmgcl3 Ni2++ Optical And Magnetic Properties Strong-field Scheme Spectrum |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/39327 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | P. F. Wu,Q. Y. Dong,S. B. Zhao,et al. D8(C3V-STAR)-EPR THEORY AND THE OPTICAL MAGNETIC-PROPERTIES OF NI2+-CSMGCL3[J]. Science in China Series a-Mathematics Physics Astronomy,1992,35(3):298-310. |
APA | P. F. Wu,Q. Y. Dong,S. B. Zhao,H. S. Wang,&K. W. Zhou.(1992).D8(C3V-STAR)-EPR THEORY AND THE OPTICAL MAGNETIC-PROPERTIES OF NI2+-CSMGCL3.Science in China Series a-Mathematics Physics Astronomy,35(3),298-310. |
MLA | P. F. Wu,et al."D8(C3V-STAR)-EPR THEORY AND THE OPTICAL MAGNETIC-PROPERTIES OF NI2+-CSMGCL3".Science in China Series a-Mathematics Physics Astronomy 35.3(1992):298-310. |
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