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D8(C3V-STAR)-EPR THEORY AND THE OPTICAL MAGNETIC-PROPERTIES OF NI2+-CSMGCL3
P. F. Wu; Q. Y. Dong; S. B. Zhao; H. S. Wang; K. W. Zhou
1992
发表期刊Science in China Series a-Mathematics Physics Astronomy
ISSN1001-6511
卷号35期号:3页码:298-310
摘要The complete strong-field-matrices for d2,8(C3v*) ions are constructed within an O(h)- point-group representation. Based on the eigenvalues and eigenvectors of these matrices, a complete-configuration-mixing EPR theory is established for Ni2+ ions in CsMgX (X = Cl, Br,I) kind crystals, and accordingly, a uniform calculation is performed for the optical absorption spectrum, the zero-field-splitting and Zeeman splitting of the ground state, the EPR parameters D and g and the EPR conditions (B,h-nu) of Ni2+ impurity ions in a CsMgCl3 crystal. The results are in very good agreement with the experimental, thus a uniform theoretical interpretation is achieved for the optical and magnetic properties of Ni2+:CsMgCl3 for the first time.
部门归属jishou univ,dept phys,jishou 416000,peoples r china. nanchong educ coll,dept phys,nanchung 637000,peoples r china. sichuan normal univ,dept chem,chengdu 610066,peoples r china. sichuan normal univ,dept phys,chengdu 610066,peoples r china. acad sinica,int ctr mat phys,shenyang,peoples r china. sichuan univ,dept phys,chengdu 610064,peoples r china.;wu, pf (reprint author), china ctr adv sci & technol,ctr theoret phys,world lab,beijing 100080,peoples r china
关键词Complete Strong-field-matrix For D2 8(C3v-star) Complete-configuration-mixing Epr Theory Csmgcl3 Ni2++ Optical And Magnetic Properties Strong-field Scheme Spectrum
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/39327
专题中国科学院金属研究所
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P. F. Wu,Q. Y. Dong,S. B. Zhao,et al. D8(C3V-STAR)-EPR THEORY AND THE OPTICAL MAGNETIC-PROPERTIES OF NI2+-CSMGCL3[J]. Science in China Series a-Mathematics Physics Astronomy,1992,35(3):298-310.
APA P. F. Wu,Q. Y. Dong,S. B. Zhao,H. S. Wang,&K. W. Zhou.(1992).D8(C3V-STAR)-EPR THEORY AND THE OPTICAL MAGNETIC-PROPERTIES OF NI2+-CSMGCL3.Science in China Series a-Mathematics Physics Astronomy,35(3),298-310.
MLA P. F. Wu,et al."D8(C3V-STAR)-EPR THEORY AND THE OPTICAL MAGNETIC-PROPERTIES OF NI2+-CSMGCL3".Science in China Series a-Mathematics Physics Astronomy 35.3(1992):298-310.
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