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STRUCTURE AND MAGNETIC-PROPERTIES OF (ND, PR)2FE14(B, C) COMPOUNDS
Z. G. Zhao; X. K. Sun; Q. Wan; W. Liu; Z. D. Zhang; Y. C. Chuang; F. R. Deboer
1991
Source PublicationJournal of Magnetism and Magnetic Materials
ISSN0304-8853
Volume97Issue:1-3Pages:79-82
AbstractStructure and magnetic properties of (Nd1-xPr(x))2Fe14B1-yC(y) compounds with x = 0, 0.2, 0.4, 0.6, 0.8, 1 and y = 0, 0.5, 1 have been studied by X-ray diffraction, ac initial susceptibility measurements and by using the SPD (singular point detection) technique. Compounds with the Nd2Fe14B-type structure were found for y = 0, 0.5 and a R2Fe17C(x) phase with R2Fe17-type structure exists for y = 1. For y = 0 and 0.5, both the Curie temperature (T(c)) and the spin-reorientation temperature (T(sr)) decrease with increasing Pr content. Spin reorientations were observed up to x = 0.8. Substitution of carbon for boron results in decrease of T(c) and T(sr), whereas it enhances the uniaxial magnetocrystalline anisotropy field. An anomalous 4f-sublattice-composition dependence of the anisotropy field is found at 290 K for the compositions with y = 0 and 0.5 which may be associated with the valence instability of the Pr ions in these systems. The experimental results show that the substitution of C for B influences the 4f sublattice as well as the 3d sublattice.
description.departmentacad sinica,int ctr mat phys,shenyang 110015,peoples r china. univ amsterdam,nat lab,1018 xe amsterdam,netherlands.;zhao, zg (reprint author), acad sinica,inst met res,shenyang 110015,peoples r china
KeywordRare-earth Compounds R2fe14c
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Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/39511
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
Z. G. Zhao,X. K. Sun,Q. Wan,et al. STRUCTURE AND MAGNETIC-PROPERTIES OF (ND, PR)2FE14(B, C) COMPOUNDS[J]. Journal of Magnetism and Magnetic Materials,1991,97(1-3):79-82.
APA Z. G. Zhao.,X. K. Sun.,Q. Wan.,W. Liu.,Z. D. Zhang.,...&F. R. Deboer.(1991).STRUCTURE AND MAGNETIC-PROPERTIES OF (ND, PR)2FE14(B, C) COMPOUNDS.Journal of Magnetism and Magnetic Materials,97(1-3),79-82.
MLA Z. G. Zhao,et al."STRUCTURE AND MAGNETIC-PROPERTIES OF (ND, PR)2FE14(B, C) COMPOUNDS".Journal of Magnetism and Magnetic Materials 97.1-3(1991):79-82.
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