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Study of the in situ growth mechanism of Mg-Al hydrotalcite conversion film on AZ31 magnesium alloy
J. Chen; Y. W. Song; D. Y. Shan; E. H. Han
2012
发表期刊Corrosion Science
ISSN0010-938X
卷号63页码:148-158
摘要By means of X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), open circuit potential (OCP) measurement and scanning electronic microscope (SEM), the in situ growth mechanism of the Mg-Al hydrotalcite film has been proposed. The composition and morphology of the films undergo a series of variations during the growth processes. The added Al compounds are a vital contribution to the formation of hydrotalcite. The film formation involves the dissolution of the AZ31 substrate, adsorption of the ions from solution, nucleation of the precursor, followed by the dissolution of Al3+, exchanging of OH- by CO32- and growth of the hydrotalcite film. (C) 2012 Elsevier Ltd. All rights reserved.
部门归属[chen, jun; song, yingwei; shan, dayong; han, en-hou] chinese acad sci, state key lab corros & protect, inst met res, shenyang 110016, peoples r china.;song, yw (reprint author), chinese acad sci, state key lab corros & protect, inst met res, 62 wencui rd, shenyang 110016, peoples r china.;ywsong@imr.ac.cn
关键词Magnesium Xps Xrd Sem Passive Films Layered Double Hydroxides Corrosion-resistance Carbonic-acid Coatings Crystallization Zn Chemistry Aluminum Steel
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/59904
专题中国科学院金属研究所
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J. Chen,Y. W. Song,D. Y. Shan,et al. Study of the in situ growth mechanism of Mg-Al hydrotalcite conversion film on AZ31 magnesium alloy[J]. Corrosion Science,2012,63:148-158.
APA J. Chen,Y. W. Song,D. Y. Shan,&E. H. Han.(2012).Study of the in situ growth mechanism of Mg-Al hydrotalcite conversion film on AZ31 magnesium alloy.Corrosion Science,63,148-158.
MLA J. Chen,et al."Study of the in situ growth mechanism of Mg-Al hydrotalcite conversion film on AZ31 magnesium alloy".Corrosion Science 63(2012):148-158.
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