The electron paramagnetic resonance (EPR) spectral data (the g factors and hyperfine structure constants) and d-d transition spectra for the tetragonal Mo5+ centre in [Mo6O19][N(C4H9)(4)](3) salt are theoretically investigated from the complete diagonalization method (CDM) for a 4d(1) ion in tetragonally compressed octahedron. The theoretical results are in good agreement with the experimental data. The dependency of the g factors of the ground state on the R-parallel to(Mo-O bond length) has been studied. It is shown that the g factors varied with the R-parallel to approximately in a linear way. (C) 2012 Elsevier B.V. All rights reserved.
部门归属
[feng, wen-lin] chongqing key lab time grating sensing & adv test, chongqing 400054, peoples r china. [feng, wen-lin] chongqing univ technol, dept appl phys, chongqing 400054, peoples r china. [feng, wen-lin] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;feng, wl (reprint author), chongqing key lab time grating sensing & adv test, chongqing 400054, peoples r china.;wenlinfeng@126.com
W. L. Feng. Theoretical investigation of EPR and optical spectra of Mo(V) in Mo6O19 N(C4H9)(4) (3) salt[J]. Journal of Magnetism and Magnetic Materials,2012,324(23):4061-4063.
APA
W. L. Feng.(2012).Theoretical investigation of EPR and optical spectra of Mo(V) in Mo6O19 N(C4H9)(4) (3) salt.Journal of Magnetism and Magnetic Materials,324(23),4061-4063.
MLA
W. L. Feng."Theoretical investigation of EPR and optical spectra of Mo(V) in Mo6O19 N(C4H9)(4) (3) salt".Journal of Magnetism and Magnetic Materials 324.23(2012):4061-4063.
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