The Raman spectra and electronic spin resonance (ESR) parameters (spin-Hamiltonian parameter g factors, zero-field splitting parameter D, and hyperfine structure constant A) for the trigonal V3+ centers in salt guanidinium vanadium sulfate hexahydrate (GVSH) are calculated from the complete diagonalization (of energy matrix) method. The theoretical results are in agreement with the experimental findings and the trigonal crystal-field parameters are determined. The difficulty in explaining ESR parameters of V3+ in GVSH is removed.
部门归属
[feng, wen-lin] chongqing univ technol, dept appl phys, chongqing 400054, peoples r china. [feng, wen-lin] chongqing key lab time grating sensing & adv test, chongqing 400054, peoples r china. [feng, wen-lin] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;feng, wl (reprint author), chongqing univ technol, dept appl phys, chongqing 400054, peoples r china.;wenlinfeng@126.com
W. L. Feng. Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate[J]. Philosophical Magazine Letters,2012,92(8):368-372.
APA
W. L. Feng.(2012).Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate.Philosophical Magazine Letters,92(8),368-372.
MLA
W. L. Feng."Theoretical explanation for Raman and ESR spectra of V3+ ions in salt guanidinium vanadium sulfate hexahydrate".Philosophical Magazine Letters 92.8(2012):368-372.
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