Oxidation and electrical behavior of ferritic stainless steel interconnect with Fe-Co-Ni coating by electroplating | |
S. J. Geng; S. J. Qi; D. Xiang; S. L. Zhu; F. H. Wang | |
2012 | |
发表期刊 | Journal of Power Sources
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ISSN | 0378-7753 |
卷号 | 215页码:274-278 |
摘要 | Fe-Co-Ni coating is deposited on ferritic stainless steel using a cost-effective technique of electroplating for intermediate-temperature solid oxide fuel cell (SOFC) interconnects application. The steel with Fe-Co-Ni coating has been evaluated in air at 800 degrees C corresponding to the cathode environment of SOFC. The results indicate that the steel with Fe-Co-Ni coating experiences an initially large mass gain, and then the mass gain increases slightly after the first-week rapid oxidation stage. After thermal exposure in air at 800 degrees C, the Fe-Co-Ni coating has been converted into (Fe,Co,Ni)(3)O-4 spinel layer underneath which a Cr2O3 layer is developed from the steel substrate. The outer layer of (Fe,Co,Ni)(3)O-4 spinel has not only suppressed Cr migration outward but also reduced the growth rate of the inner layer of Cr2O3. The steel with Fe-Co-Ni coating exhibits a stable surface oxide scale area specific resistance (ASR) which is much lower than that of the bare steel. (Fe,Co,Ni)(3)O-4 spinel is a promising protective coating for SOFC steel interconnect. (C) 2012 Elsevier B.V. All rights reserved. |
部门归属 | [geng, shujiang; qi, shaojun; xiang, dong] northeastern univ, sch met & mat, shenyang 110819, peoples r china. [geng, shujiang; zhu, shenglong; wang, fuhui] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china.;geng, sj (reprint author), northeastern univ, sch met & mat, box 119,3-11 wenhua rd, shenyang 110819, peoples r china.;gengsj@smm.neu.edu.cn |
关键词 | Solid Oxide Fuel Cell Electroplated Fe-co-ni Coating Interconnect Oxidation Area Specific Resistance Oxide Fuel-cells Chromium-containing Alloy Sofc Interconnects Protection Layers Metallic Interconnects Doped Lagao3 Cathode Spinel Conductivity Temperature |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/59963 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | S. J. Geng,S. J. Qi,D. Xiang,et al. Oxidation and electrical behavior of ferritic stainless steel interconnect with Fe-Co-Ni coating by electroplating[J]. Journal of Power Sources,2012,215:274-278. |
APA | S. J. Geng,S. J. Qi,D. Xiang,S. L. Zhu,&F. H. Wang.(2012).Oxidation and electrical behavior of ferritic stainless steel interconnect with Fe-Co-Ni coating by electroplating.Journal of Power Sources,215,274-278. |
MLA | S. J. Geng,et al."Oxidation and electrical behavior of ferritic stainless steel interconnect with Fe-Co-Ni coating by electroplating".Journal of Power Sources 215(2012):274-278. |
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