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Oxidation and electrical behavior of ferritic stainless steel interconnect with Fe-Co-Ni coating by electroplating
S. J. Geng; S. J. Qi; D. Xiang; S. L. Zhu; F. H. Wang
2012
发表期刊Journal of Power Sources
ISSN0378-7753
卷号215页码:274-278
摘要Fe-Co-Ni coating is deposited on ferritic stainless steel using a cost-effective technique of electroplating for intermediate-temperature solid oxide fuel cell (SOFC) interconnects application. The steel with Fe-Co-Ni coating has been evaluated in air at 800 degrees C corresponding to the cathode environment of SOFC. The results indicate that the steel with Fe-Co-Ni coating experiences an initially large mass gain, and then the mass gain increases slightly after the first-week rapid oxidation stage. After thermal exposure in air at 800 degrees C, the Fe-Co-Ni coating has been converted into (Fe,Co,Ni)(3)O-4 spinel layer underneath which a Cr2O3 layer is developed from the steel substrate. The outer layer of (Fe,Co,Ni)(3)O-4 spinel has not only suppressed Cr migration outward but also reduced the growth rate of the inner layer of Cr2O3. The steel with Fe-Co-Ni coating exhibits a stable surface oxide scale area specific resistance (ASR) which is much lower than that of the bare steel. (Fe,Co,Ni)(3)O-4 spinel is a promising protective coating for SOFC steel interconnect. (C) 2012 Elsevier B.V. All rights reserved.
部门归属[geng, shujiang; qi, shaojun; xiang, dong] northeastern univ, sch met & mat, shenyang 110819, peoples r china. [geng, shujiang; zhu, shenglong; wang, fuhui] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china.;geng, sj (reprint author), northeastern univ, sch met & mat, box 119,3-11 wenhua rd, shenyang 110819, peoples r china.;gengsj@smm.neu.edu.cn
关键词Solid Oxide Fuel Cell Electroplated Fe-co-ni Coating Interconnect Oxidation Area Specific Resistance Oxide Fuel-cells Chromium-containing Alloy Sofc Interconnects Protection Layers Metallic Interconnects Doped Lagao3 Cathode Spinel Conductivity Temperature
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/59963
专题中国科学院金属研究所
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S. J. Geng,S. J. Qi,D. Xiang,et al. Oxidation and electrical behavior of ferritic stainless steel interconnect with Fe-Co-Ni coating by electroplating[J]. Journal of Power Sources,2012,215:274-278.
APA S. J. Geng,S. J. Qi,D. Xiang,S. L. Zhu,&F. H. Wang.(2012).Oxidation and electrical behavior of ferritic stainless steel interconnect with Fe-Co-Ni coating by electroplating.Journal of Power Sources,215,274-278.
MLA S. J. Geng,et al."Oxidation and electrical behavior of ferritic stainless steel interconnect with Fe-Co-Ni coating by electroplating".Journal of Power Sources 215(2012):274-278.
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