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A study of the evolution of rust on Mo-Cu-bearing fire-resistant steel submitted to simulated atmospheric corrosion
L. Hao; S. X. Zhang; J. H. Dong; W. Ke
2012
发表期刊Corrosion Science
ISSN0010-938X
卷号54页码:244-250
摘要The corrosion evolution of a Mo-Cu-bearing fire-resistant steel in a simulated industrial atmosphere was investigated by corrosion weight gain, XRD, EPMA, XPS, and polarization curves. The results indicate that the corrosion kinetics is closely related to the rust composition and electrochemical properties. As the corrosion proceeds, the relative content of gamma-FeOOH and Fe(3)O(4) decreases and alpha-FeOOH increases, and the rust layer becomes compact and adherent to steel substrate. Molybdenum and copper enrich in the inner rust layer, especially at the bottom of the corrosion nest, forming non-soluble molybdate and Cu(I)-bearing compounds responsible for enhanced corrosion resistance of the rust layer. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.
部门归属[hao, long; dong, junhua; ke, wei] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. [zhang, sixun] northeastern univ, coll mat & met, shenyang 110004, peoples r china. [zhang, sixun] tech ctr laiwu steel grp ltd, laiwu 271104, peoples r china.;dong, jh (reprint author), chinese acad sci, inst met res, state key lab corros & protect, wencui rd 62, shenyang 110016, peoples r china.;jhdong@imr.ac.cn
关键词Low Alloy Steel Xrd Epma Xps Atmospheric Corrosion Rust Low-alloy Steel Weathering Steel Carbon-steel Field Exposure Chemical-state Iron Environments Performance Copper Spectroscopy
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/59992
专题中国科学院金属研究所
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GB/T 7714
L. Hao,S. X. Zhang,J. H. Dong,et al. A study of the evolution of rust on Mo-Cu-bearing fire-resistant steel submitted to simulated atmospheric corrosion[J]. Corrosion Science,2012,54:244-250.
APA L. Hao,S. X. Zhang,J. H. Dong,&W. Ke.(2012).A study of the evolution of rust on Mo-Cu-bearing fire-resistant steel submitted to simulated atmospheric corrosion.Corrosion Science,54,244-250.
MLA L. Hao,et al."A study of the evolution of rust on Mo-Cu-bearing fire-resistant steel submitted to simulated atmospheric corrosion".Corrosion Science 54(2012):244-250.
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