Three-Dimensional Hierarchically Ordered Porous Carbons with Partially Graphitic Nanostructures for Electrochemical Capacitive Energy Storage

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	Three-Dimensional Hierarchically Ordered Porous Carbons with Partially Graphitic Nanostructures for Electrochemical Capacitive Energy Storage
	C. H. Huang; Q. Zhang; T. C. Chou; C. M. Chen; D. S. Su; R. A. Doong
	2012
发表期刊	Chemsuschem
ISSN	1864-5631
卷号	5 期号:3 页码:563-571
摘要	Three-dimensional, hierarchically ordered, porous carbon (HOPC) with designed porous textures, serving as an ion-buffering reservoir, an ion-transport channel, and a charge-storage material, is expected to be advanced an energy material for high-rate supercapacitors. Herein, HOPC without/with partially graphitic nanostructures have been directly synthesized by means of a simple one-pot synthesis procedure. The designed porous textures of the 3D HOPC materials are composed of highly ordered, fcc macroporous (300 nm), interconnected porous structures, including macroporous windows (170 nm), hexagonally ordered mesopores (5.0 nm), and useful micropores (1.2 nm). 3D HOPC-g-1000 (g=graphitic, 1000=pyrolysis temperature of 1000 degrees C) with partially graphitic nanostructures has a low specific surface area (296 m2 g-1) and a low gravimetric specific capacitance (73.4 F g-1 at 3 mV s-1), but improved electrical conductivity, better rate performance, higher electrolyte accessibility (24.8 mu F cm-2 at 3 mV s-1), faster frequency response (similar to 1 Hz), and excellent cycling performance (>5400 cycles). The specific capacitance per surface area is higher than that of conventional porous carbons, carbon nanotubes, and modified graphene (10-19 mu F cm(-2)).
部门归属	[huang, chun-hsien; zhang, qiang; chen, cheng-meng; su, dang sheng] max planck soc, dept inorgan chem, fritz haber inst, d-14195 berlin, germany. [huang, chun-hsien; chou, tsu-chin; doong, ruey-an] natl tsing hua univ, dept biomed engn & environm sci, hsinchu 30013, taiwan. [zhang, qiang] tsinghua univ, dept chem engn, beijing 100084, peoples r china. [chen, cheng-meng] chinese acad sci, inst coal chem, key lab carbon mat, taiyuan 030001, peoples r china. [su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;su, ds (reprint author), max planck soc, dept inorgan chem, fritz haber inst, faradayweg 4-6, d-14195 berlin, germany.;dangsheng@fhi-berlin.mpg.de; radoong@mx.nthu.edu.tw
关键词	Carbon Electrochemistry Energy Storage Nanostructures Supercapacitors High-surface-area Supercapacitor Electrodes Mesoporous Carbons High-performance Macroporous Carbon Recent Progress Nanotubes Nexafs
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文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/60005
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	C. H. Huang,Q. Zhang,T. C. Chou,et al. Three-Dimensional Hierarchically Ordered Porous Carbons with Partially Graphitic Nanostructures for Electrochemical Capacitive Energy Storage[J]. Chemsuschem,2012,5(3):563-571.
APA	C. H. Huang,Q. Zhang,T. C. Chou,C. M. Chen,D. S. Su,&R. A. Doong.(2012).Three-Dimensional Hierarchically Ordered Porous Carbons with Partially Graphitic Nanostructures for Electrochemical Capacitive Energy Storage.Chemsuschem,5(3),563-571.
MLA	C. H. Huang,et al."Three-Dimensional Hierarchically Ordered Porous Carbons with Partially Graphitic Nanostructures for Electrochemical Capacitive Energy Storage".Chemsuschem 5.3(2012):563-571.