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Phase Diagrams of the Zr-Si-RE (RE=La and Er) Ternary Systems at 773 K (500 A degrees C)
C. L. Li; Y. Z. Zhan; J. She; Q. X. Huang; M. J. Pang; W. C. Yang
2012
发表期刊Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science
ISSN1073-5623
卷号43A期号:1页码:20-28
摘要The isothermal sections of the phase diagram of the Zr-Si-RE (RE=La and Er) systems at 773 K (500 A degrees C) have been investigated using X-ray power diffraction (XRD), scanning electron microscopy (SEM), and optical microscopy (OM) with the aid of metallographic analysis. The existences of 10 binary compounds, namely ZrSi(2), alpha-ZrSi, alpha-Zr(5)Si(4), Zr(3)Si(2), Zr(2)Si, RESi(2), RESi(2-x) , RESi, RE(5)Si(4), and RE(5)Si(3) have been confirmed in the Zr-Si-RE (RE=La and Er) systems, respectively. As for the reported binary compound RE(3)Si(2), only La(3)Si(2) has been observed in the Zr-Si-La system, whereas Er(3)Si(2) was not found. No binary compound was found in the Zr-RE binary systems, and no ternary compound was found in the current ternary systems. None of the phases in Zr-Si-La system reveals a remarkable solid solution at 773 K (500 A degrees C). However, the maximum solid solubility of Zr in Er, Er(5)Si(3), Er(5)Si(4), ErSi, ErSi(1.67), and ErSi(2) is determined to be approximately 12.0 at. pct, 2.4 at. pct, 3.0 at. pct, 3.3 at. pct, 2.2 at. pct, and 1.8 at. pct, respectively. The maximum solid solubility of Er in ErSi(2) is approximately 1.8 at. pct. No remarkable solid solubility of the elements in any of the other phases has been observed.
部门归属[li, chunliu; zhan, yongzhong; she, jia; huang, qingxiao; pang, mingjun; yang, wenchao] guangxi univ, lab nonferrous met mat & new proc technol, minist educ, nanning 530004, guangxi, peoples r china. [zhan, yongzhong] chinese acad sci, int ctr mat phys, shenyang 10016, peoples r china.;li, cl (reprint author), guangxi univ, lab nonferrous met mat & new proc technol, minist educ, nanning 530004, guangxi, peoples r china.;zyzmatres@yahoo.com.cn
关键词Silicon System Alloys Equilibria Silicides Hydrogen
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/60047
专题中国科学院金属研究所
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GB/T 7714
C. L. Li,Y. Z. Zhan,J. She,et al. Phase Diagrams of the Zr-Si-RE (RE=La and Er) Ternary Systems at 773 K (500 A degrees C)[J]. Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science,2012,43A(1):20-28.
APA C. L. Li,Y. Z. Zhan,J. She,Q. X. Huang,M. J. Pang,&W. C. Yang.(2012).Phase Diagrams of the Zr-Si-RE (RE=La and Er) Ternary Systems at 773 K (500 A degrees C).Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science,43A(1),20-28.
MLA C. L. Li,et al."Phase Diagrams of the Zr-Si-RE (RE=La and Er) Ternary Systems at 773 K (500 A degrees C)".Metallurgical and Materials Transactions a-Physical Metallurgy and Materials Science 43A.1(2012):20-28.
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