Phase formation and microstructure evolution of arc ion deposited Cr2AlC coating after heat treatment | |
J. J. Li; Y. H. Qian; D. Niu; M. M. Zhang; Z. M. Liu; M. S. Li | |
2012 | |
发表期刊 | Applied Surface Science
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ISSN | 0169-4332 |
卷号 | 263页码:457-464 |
摘要 | Due to the excellent oxidation and hot corrosion resistance and matched thermal expansion coefficient to normal alloys, Cr2AlC has potential applications as high-temperature protective coating. In the present work, the preparation of Cr2AlC coating has been achieved through cathodic arc deposition method combined with heat post-treatment. It was found that the coating, deposited from Cr2AlC compound target in the unintentional heating condition, was amorphous. After annealing at 620 degrees C in Ar for 20 h, the amorphous Cr-Al-C coating happened to crystallize and transformed to crystalline Cr2AlC as the major phase. It is obvious that the formation temperature of Cr2AlC was decreased from about 1050 degrees C for sintered bulk to around 620 degrees C for the as-deposited coating, resulting from the homogeneous mixture of the Cr, Al and C at atomic level in the Cr-Al-C coating. Apart from crystalline Cr2AlC, the annealed coating also contained AlCr2 and little Cr7C3. AlCr2 formed due to the loss of C during deposition, and little Cr7C3 always existed in the sintered Cr2AlC compound target as impurity phase. (C) 2012 Elsevier B. V. All rights reserved. |
部门归属 | [li, j. j.; qian, y. h.; liu, z. m.; li, m. s.] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. [li, j. j.; liu, z. m.] chinese acad sci, grad sch, beijing 100039, peoples r china. [niu, d.; zhang, m. m.] northeast univ, shenyang 110016, peoples r china.;li, ms (reprint author), 72 wenhua rd, shenyang 110016, peoples r china.;mshli@imr.ac.cn |
关键词 | Cr2alc Coating Cathodic Arc Deposition Microstructure n Thin-films Degrees-c m(n+1)Ax(n) Phases Thermal-stability Bulk Cr2alc Oxidation Ti Evaporation Corrosion Behavior |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/60056 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. J. Li,Y. H. Qian,D. Niu,et al. Phase formation and microstructure evolution of arc ion deposited Cr2AlC coating after heat treatment[J]. Applied Surface Science,2012,263:457-464. |
APA | J. J. Li,Y. H. Qian,D. Niu,M. M. Zhang,Z. M. Liu,&M. S. Li.(2012).Phase formation and microstructure evolution of arc ion deposited Cr2AlC coating after heat treatment.Applied Surface Science,263,457-464. |
MLA | J. J. Li,et al."Phase formation and microstructure evolution of arc ion deposited Cr2AlC coating after heat treatment".Applied Surface Science 263(2012):457-464. |
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