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alpha-Sulfur Crystals as a Visible-Light-Active Photocatalyst
G. Liu; P. Niu; L. C. Yin; H. M. Cheng
2012
发表期刊Journal of the American Chemical Society
ISSN0002-7863
卷号134期号:22页码:9070-9073
摘要We show that in contrast to conventional compound photocatalysts, alpha-sulfur crystals of cyclo-octasulfur (S-8) are a visible-light-active elemental photocatalyst. The alpha-S crystals were found to have the ability not only to generate center dot OH radicals but also to split water in a photoelectrochemical process under both UV-vis and visible-light irradiation. Although the absolute activity obtained was low because of the large particle size and poor hydrophilicity of the alpha-S crystals studied, there is great potential for increasing the activity with the assistance of known strategies such as surface modification, nanoscaling, doping, and coupling with other photocatalysts.
部门归属[liu, gang; niu, ping; yin, lichang; cheng, hui-ming] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;cheng, hm (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china.;cheng@imr.ac.cn
关键词Hydrogen-production Water
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/60107
专题中国科学院金属研究所
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GB/T 7714
G. Liu,P. Niu,L. C. Yin,et al. alpha-Sulfur Crystals as a Visible-Light-Active Photocatalyst[J]. Journal of the American Chemical Society,2012,134(22):9070-9073.
APA G. Liu,P. Niu,L. C. Yin,&H. M. Cheng.(2012).alpha-Sulfur Crystals as a Visible-Light-Active Photocatalyst.Journal of the American Chemical Society,134(22),9070-9073.
MLA G. Liu,et al."alpha-Sulfur Crystals as a Visible-Light-Active Photocatalyst".Journal of the American Chemical Society 134.22(2012):9070-9073.
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