LiBH4 center dot NH3BH3: A new lithium borohydride ammonia borane compound with a novel structure and favorable hydrogen storage properties

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	LiBH4 center dot NH3BH3: A new lithium borohydride ammonia borane compound with a novel structure and favorable hydrogen storage properties
	J. H. Luo; H. Wu; W. Zhou; X. D. Kang; Z. Z. Fang; P. Wang
	2012
Source Publication	International Journal of Hydrogen Energy
ISSN	0360-3199
Volume	37 Issue:14 Pages:10750-10757
Abstract	Mechanically milling milling ammonia borane and lithium borohydride in equivalent molar ratio results in the formation of a new complex, LiBH4 center dot NH3BH3. Its structure was successfully determined using combined X-ray diffraction and first-principles calculations. LiBH4 center dot NH3BH3 was carefully studied in terms of its decomposition behavior and reversible dehydrogenation property, particularly in comparison with the component phases. In parallel to the property examination, X-ray diffraction and Fourier transformation infrared spectroscopy techniques were employed to monitor the phase evolution and bonding structure changes in the reaction process. Our study found that LiBH4 center dot NH3BH3 first disproportionates into (LiBH4)(2)center dot NH3BH3 and NH3BH3, and the resulting mixture exhibits a three-step decomposition behavior upon heating to 450 degrees C, totally yielding similar to 15.7 wt% hydrogen. Interestingly, it was found that h-BN was formed at such a moderate temperature. And owing to the in situ formation of h-BN, LiBH4 center dot NH3BH3 exhibits significantly improved reversible dehydrogenation properties in comparison with the LiBH4 phase. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
description.department	[luo, junhong; kang, xiangdong; fang, zhanzhao; wang, ping] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. [wu, hui; zhou, wei] natl inst stand & technol, nist ctr neutron res, gaithersburg, md 20899 usa. [wu, hui; zhou, wei] univ maryland, dept mat sci & engn, college pk, md 20742 usa.;wang, p (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china.;huiwu@nist.gov; pingwang@imr.ac.cn
Keyword	Hydrogen Storage Ammonia Borane Lithium Borohydride Dehydrogenation Bn Thermal-decomposition Generation System Crystal-structure Dehydrogenation Amidoborane Release Amidotrihydroborate Regeneration Dissociation Hydrolysis
URL	查看原文
Document Type	期刊论文
Identifier	http://ir.imr.ac.cn/handle/321006/60144
Collection	中国科学院金属研究所
Recommended Citation GB/T 7714	J. H. Luo,H. Wu,W. Zhou,et al. LiBH4 center dot NH3BH3: A new lithium borohydride ammonia borane compound with a novel structure and favorable hydrogen storage properties[J]. International Journal of Hydrogen Energy,2012,37(14):10750-10757.
APA	J. H. Luo,H. Wu,W. Zhou,X. D. Kang,Z. Z. Fang,&P. Wang.(2012).LiBH4 center dot NH3BH3: A new lithium borohydride ammonia borane compound with a novel structure and favorable hydrogen storage properties.International Journal of Hydrogen Energy,37(14),10750-10757.
MLA	J. H. Luo,et al."LiBH4 center dot NH3BH3: A new lithium borohydride ammonia borane compound with a novel structure and favorable hydrogen storage properties".International Journal of Hydrogen Energy 37.14(2012):10750-10757.

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