Controlled Hydrogen Generation by Reaction of Aluminum with Water

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	Controlled Hydrogen Generation by Reaction of Aluminum with Water
	G. L. Ma; D. W. Zhuang; H. Dai; P. Wang
	2012
发表期刊	Progress in Chemistry
ISSN	1005-281X
卷号	24 期号:4 页码:650-658
摘要	Aluminum is the most abundant crustal metallic element on the earth and 100% recycled in theory. Controlled hydrogen generation (HG) by reaction of aluminum with water could provide a renewable energy cycle to address the global energy problem. In this perspective, we present the state of art in the principle, mechanism, approaches, and hydrogen generator of HG from the reaction of aluminum with water, and further discuss some remaining problems in the development of aluminum-based HG system. The key to the HG by the reaction of aluminum with water is how to disrupt/inhibit a native/regeneration coherent and adherent passivation film of aluminum surface. The fast kinetics is desirable in developing the aluminum-based HG system for the practical application. The design of hydrogen generator should focus on the utilization of reaction heat to preheat fuel, the recycle of water from the fuel cell, the fuel cartridges and the process of separation by the membrane. The use of recycled scrap aluminum will provide a reasonable hydrogen cost, thus promoting its commercial applications.
部门归属	[ma guanglu; zhuang dawei; dai hongbin; wang ping] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china.;dai, h (reprint author), chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china.;hbdai@imr.ac.cn; pingwang@imr.ac.cn
关键词	Aluminum Hydrogen Generation Reaction Kinetics Hydrogen Generator Membrane Fuel-cells Sodium-borohydride Splitting Water Al Hydrolysis Corrosion Alloys Microstructure Performance Mechanism
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/60151
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	G. L. Ma,D. W. Zhuang,H. Dai,et al. Controlled Hydrogen Generation by Reaction of Aluminum with Water[J]. Progress in Chemistry,2012,24(4):650-658.
APA	G. L. Ma,D. W. Zhuang,H. Dai,&P. Wang.(2012).Controlled Hydrogen Generation by Reaction of Aluminum with Water.Progress in Chemistry,24(4),650-658.
MLA	G. L. Ma,et al."Controlled Hydrogen Generation by Reaction of Aluminum with Water".Progress in Chemistry 24.4(2012):650-658.