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Preparation and Electrochemical Properties of Polyaniline Nanofiber Modified Graphite Foil
X. G. Sang; F. W. Zeng; X. X. Liu
2012
发表期刊Chemical Journal of Chinese Universities-Chinese
ISSN0251-0790
卷号33期号:6页码:1312-1318
摘要Polyaniline nanofiber(Nano-PANI) modified graphite foil(GE) (Nano-PANI/GF) was prepared by electrochemical polymerization of aniline on GF electrode. The polymer on the modified electrode Nano-PANI/GE was characterized by FTIR. The morphologies of the modified electrode were investigated by SEM. The Nano-PANI/GF electrode made through cyclic voltammetric scans in a solution of 0. 1 mol/L aniline and 1. 0 mol/L HCl showed good electroactivites in 0. 1 mol/L phosphate buffer solution( pH = 6. 9). The electrocatalytic properties of the modified electrode toward ascorbic acid oxidation were studied through cyclic voltammetry and potentiometry. The current for ascorbic acid oxidation on the modified electrode at 0. 2 V showed linear response to the concentration of ascorbic acid in the range of 1. 7-2. 0x10(3) mu mol/L. The detection limit of ascorbic acid on the modified electrode is 1. 7 mu mol/L(S/N =3).
部门归属[sang xiao-guang; liu xiao-xia] northeastern univ, dept chem, shenyang 110819, peoples r china. [zeng fan-wu] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;liu, xx (reprint author), northeastern univ, dept chem, shenyang 110819, peoples r china.;xxliu@mail.neu.edu.cn
关键词Polyaniline Nanofiber Graphite Foil Electrocatalysis Ascorbic Acid Glassy-carbon Electrode Cholesterol Biosensor Adenine-dinucleotide Conducting Polymer Ascorbic-acid Film Composites Nanotubes Oxidation Immobilization
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/60204
专题中国科学院金属研究所
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X. G. Sang,F. W. Zeng,X. X. Liu. Preparation and Electrochemical Properties of Polyaniline Nanofiber Modified Graphite Foil[J]. Chemical Journal of Chinese Universities-Chinese,2012,33(6):1312-1318.
APA X. G. Sang,F. W. Zeng,&X. X. Liu.(2012).Preparation and Electrochemical Properties of Polyaniline Nanofiber Modified Graphite Foil.Chemical Journal of Chinese Universities-Chinese,33(6),1312-1318.
MLA X. G. Sang,et al."Preparation and Electrochemical Properties of Polyaniline Nanofiber Modified Graphite Foil".Chemical Journal of Chinese Universities-Chinese 33.6(2012):1312-1318.
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