Synthesis of Single-Crystal TiO2 Nanowire Using Titanium Monoxide Powder by Thermal Evaporation | |
Z. G. Shang; Z. Q. Liu; P. J. Shang; J. K. Shang | |
2012 | |
发表期刊 | Journal of Materials Science & Technology
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ISSN | 1005-0302 |
卷号 | 28期号:5页码:385-390 |
摘要 | TiO2 nanowires were synthesized successfully in a large quantity by thermal evaporation using titanium monoxide powder as precursor. X-ray diffraction results showed that all the products were pure rutile phase of TiO2. According to microstructural observations, the nanowires have two typical morphologies, a long straight type and a short tortuous type. The straight nanowires were obtained at a wide temperature range of 900-1050 degrees C, while the tortuous ones were formed below 900 degrees C. Transmission electron microscopy characterization revealed that both the straight and the tortuous nanowires are single-crystal rutile TiO2. The preferential growth direction of the nanowires was determined as [110] orientation according to electron diffraction and high-resolution image analyses. The morphological change of TiO2 nanowires was discussed by considering the different atomic diffusion rates of Ti atoms caused by the phase transformation in Ti substrate at around 900 degrees C. |
部门归属 | [shang, z. g.; liu, z. q.; shang, p. j.; shang, j. k.] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;liu, zq (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.;zqliu@imr.ac.cn |
关键词 | Rutile-tio2 Alloy Nanowires Transmission Electron Microscopy (Tem) Characterization Crystal Structure Identification Growth Mechanism Thermal Evaporation Sensitized Solar-cells Thin-film Growth Mechanism Rutile Gas Degradation Temperature Surface Arrays |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/60207 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | Z. G. Shang,Z. Q. Liu,P. J. Shang,et al. Synthesis of Single-Crystal TiO2 Nanowire Using Titanium Monoxide Powder by Thermal Evaporation[J]. Journal of Materials Science & Technology,2012,28(5):385-390. |
APA | Z. G. Shang,Z. Q. Liu,P. J. Shang,&J. K. Shang.(2012).Synthesis of Single-Crystal TiO2 Nanowire Using Titanium Monoxide Powder by Thermal Evaporation.Journal of Materials Science & Technology,28(5),385-390. |
MLA | Z. G. Shang,et al."Synthesis of Single-Crystal TiO2 Nanowire Using Titanium Monoxide Powder by Thermal Evaporation".Journal of Materials Science & Technology 28.5(2012):385-390. |
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