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Improved corrosion performance of electrophoretic coatings by silane addition
L. K. Wu; J. T. Zhang; J. M. Hu; J. Q. Zhang
2012
发表期刊Corrosion Science
ISSN0010-938X
卷号56页码:58-66
摘要Organosilanes are incorporated into a commercial cathodic electrophoretic paint, resulting in significant improvement in the long-term corrosion protective properties of the paint. The addition of organosilanes have strengthened mechanical properties, improved hydrophobicity, lowered water uptake and less decrease in glass transition temperature of the coatings, suggesting the enhancement in bulk structure of the polymeric coatings. In addition, silane-enriched layer preferentially forms at the metal/coating interface during the electrophoresis process, leading to better adhesion between the substrate and the coating. The structural enhancement in both the coating and the metal/coating interface explains the improved corrosion performance of silane-incorporated electrophoretic coatings. (C) 2011 Elsevier Ltd. All rights reserved.
部门归属[wu, lian-kui; hu, ji-ming; zhang, jian-qing] zhejiang univ, dept chem, hangzhou 310027, peoples r china. [zhang, jin-tao] changzhou inst technol, dept chem engn, changzhou 213022, peoples r china. [zhang, jian-qing] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china.;hu, jm (reprint author), zhejiang univ, dept chem, hangzhou 310027, peoples r china.;kejmhu@zju.edu.cn
关键词Organic Coatings Eis Electrodeposited Films Electrochemical Impedance Spectroscopy Aa2024-t3 Aluminum-alloy Sol-gel Films Epoxy Coatings Galvanized Steel Nacl Solution Chemical-modification Protective Properties Assisted Deposition Coated Metals
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/60344
专题中国科学院金属研究所
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L. K. Wu,J. T. Zhang,J. M. Hu,et al. Improved corrosion performance of electrophoretic coatings by silane addition[J]. Corrosion Science,2012,56:58-66.
APA L. K. Wu,J. T. Zhang,J. M. Hu,&J. Q. Zhang.(2012).Improved corrosion performance of electrophoretic coatings by silane addition.Corrosion Science,56,58-66.
MLA L. K. Wu,et al."Improved corrosion performance of electrophoretic coatings by silane addition".Corrosion Science 56(2012):58-66.
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