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Facile synthesis of hierarchically porous Co3O4 nanowire arrays with enhanced electrochemical catalysis
J. Xu; J. Cai; J. M. Wang; L. Y. Zhang; Y. Q. Fan; N. Zhang; H. Zhou; D. Chen; Y. Zhong; H. Q. Fan; H. B. Shao; J. Q. Zhang; C. N. Cao
2012
发表期刊Electrochemistry Communications
ISSN1388-2481
卷号25页码:119-123
摘要We report a facile template-free procedure to synthesize freestanding Co3O4 nanowire arrays on nickel substrate. Cobalt oxalate nanowire arrays are formed by immersing the electrodeposited Co film in an oxalic acid solution, and their morphologies can be conveniently tuned by changing the composition of precursor solution. The thermal treatment of the cobalt oxalate nanowire arrays at 250 degrees C results in the formation of Co3O4 nanowire arrays. The as-synthesized Co3O4 nanowires exhibit a hierarchically porous structure inside their architectures. The Co3O4 nanowire array shows a much high sensitivity and a relatively wide linear range for the electrochemical detection of H2O2, resulting from the unique hierarchical nanostructure. (C) 2012 Elsevier B.V. All rights reserved.
部门归属[xu, jing; cai, jing; wang, jianming; zhang, liying; fan, yuqian; zhang, na; zhou, huan; chen, dan; zhong, yuan; fan, huiqing; shao, haibo; zhang, jianqing; cao, chu-nan] zhejiang univ, dept chem, hangzhou 310027, zhejiang, peoples r china. [zhang, jianqing; cao, chu-nan] chinese acad sci, inst met res, state key lab corros & protect metal, shenyang 110016, peoples r china.;wang, jm (reprint author), zhejiang univ, dept chem, hangzhou 310027, zhejiang, peoples r china.;wjm@zju.edu.cn
关键词Cobalt Oxide Nanowire Porous Structure Hydrogen Peroxide Electrochemical Detection Ion Battery Electrodes Cobalt Hydroxide Template Oxide
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/60364
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
J. Xu,J. Cai,J. M. Wang,et al. Facile synthesis of hierarchically porous Co3O4 nanowire arrays with enhanced electrochemical catalysis[J]. Electrochemistry Communications,2012,25:119-123.
APA J. Xu.,J. Cai.,J. M. Wang.,L. Y. Zhang.,Y. Q. Fan.,...&C. N. Cao.(2012).Facile synthesis of hierarchically porous Co3O4 nanowire arrays with enhanced electrochemical catalysis.Electrochemistry Communications,25,119-123.
MLA J. Xu,et al."Facile synthesis of hierarchically porous Co3O4 nanowire arrays with enhanced electrochemical catalysis".Electrochemistry Communications 25(2012):119-123.
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