Monte Carlo Simulation of the Radius of Gyration of Hyperbranched Polymers Formed in Self-condensing Vinyl Polymerization System in the Presence of Core Initiators with Unequal Reactivity

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	Monte Carlo Simulation of the Radius of Gyration of Hyperbranched Polymers Formed in Self-condensing Vinyl Polymerization System in the Presence of Core Initiators with Unequal Reactivity
	Y. Zheng; H. J. Wang
	2012
发表期刊	Chemical Journal of Chinese Universities-Chinese
ISSN	0251-0790
卷号	33 期号:1 页码:144-148
摘要	The second radius of gyration of hyperbranched polymers formed in self-condensing vinyl polymerization system in the presence of core initiators was studied by the method of Monte Carlo simulation, in which the unequal reactivity was taken into account. As a result, the roles of the reactivity differences in two types of active groups, the molar ratio and functionality of core initiators were mainly discussed, and it was found that these factors could give rise to a significant influence on the radius of gyration of hyperbranched polymers with and without a core initiator. This provides some useful clues for regulating the dimension of the hyperbranched polymers in the relevant experiments.
部门归属	[zheng yue; wang hai-jun] hebei univ, minist educ, coll chem & environm sci, baoding 071002, peoples r china. [wang hai-jun] hebei univ, minist educ, key lab med chem & mol diag, baoding 071002, peoples r china. [wang hai-jun] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;wang, hj (reprint author), hebei univ, minist educ, coll chem & environm sci, baoding 071002, peoples r china.;whj@mail.hbu.cn
关键词	Self-condensing Vinyl Polymerization Unequal Reactivity Radius Of Gyration Monte Carlo Simulation Molecular-weight Distribution Multifunctional Initiator Rate Constants Kinetic-model Parameters Monomers
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/60513
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Y. Zheng,H. J. Wang. Monte Carlo Simulation of the Radius of Gyration of Hyperbranched Polymers Formed in Self-condensing Vinyl Polymerization System in the Presence of Core Initiators with Unequal Reactivity[J]. Chemical Journal of Chinese Universities-Chinese,2012,33(1):144-148.
APA	Y. Zheng,&H. J. Wang.(2012).Monte Carlo Simulation of the Radius of Gyration of Hyperbranched Polymers Formed in Self-condensing Vinyl Polymerization System in the Presence of Core Initiators with Unequal Reactivity.Chemical Journal of Chinese Universities-Chinese,33(1),144-148.
MLA	Y. Zheng,et al."Monte Carlo Simulation of the Radius of Gyration of Hyperbranched Polymers Formed in Self-condensing Vinyl Polymerization System in the Presence of Core Initiators with Unequal Reactivity".Chemical Journal of Chinese Universities-Chinese 33.1(2012):144-148.