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Controlled hydrothermal synthesis of tri-wing tellurium nanoribbons and their template reaction
H. T. Zhu; J. Luo; H. Zhang; J. K. Liang; G. H. Rao; J. B. Li; G. Y. Liu; Z. M. Du
2012
发表期刊Crystengcomm
ISSN1466-8033
卷号14期号:1页码:251-255
摘要Single crystalline tri-wing tellurium nanoribbons with well-defined outer surfaces and geometrical shapes are synthesized by a facile hydrothermal method in the presence of poly(vinyl alcohol) as the surfactant. The tri-wing Te nanoribbons with a length of tens of micrometres have a very thin wing structure with an average thickness about 20 nm. A two-step growth mechanism is proposed for the formation of tri-wing Te nanoribbons based on time dependent morphology evolution. By adjusting the pH value of the reaction solution, varied Te nanostructures including nanofeathers, nanobelts, tri-wing nanoribbons and nanorods are obtained, indicating that the reduction rate plays a key role in fabricating tri-wing Te nanoribbons since the pH value has a dramatic influence on the reduction reaction rate of TeO32-. With tri-wing Te nanoribbons as the precursor and template, Ag2Te nanoribbons in the same shape and similar size are synthesized through the direct reaction of Te with AgNO3 at room temperature, demonstrating that the Te nanoribbons with a very thin tri-wing structure are ideal templates to synthesize other Te related nanocompounds.
部门归属[zhu, hangtian; luo, jun; zhang, he; liang, jingkui; rao, guanghui; li, jingbo; liu, guangyao] chinese acad sci, beijing natl lab condensed matter phys, inst phys, beijing 100190, peoples r china. [zhu, hangtian; zhang, he; du, zhenmin] univ sci & technol beijing, dept mat sci & engn, beijing 100083, peoples r china. [liang, jingkui] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;luo, j (reprint author), chinese acad sci, beijing natl lab condensed matter phys, inst phys, beijing 100190, peoples r china.;jluo@aphy.iphy.ac.cn
关键词One-dimensional Nanostructures Thermoelectric Transport-properties Ultrathin Te Nanowires High-aspect-ratio Growth-mechanism Room-temperature Trigonal Tellurium Nanotubes Nanorods Photoluminescence
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/60534
专题中国科学院金属研究所
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GB/T 7714
H. T. Zhu,J. Luo,H. Zhang,et al. Controlled hydrothermal synthesis of tri-wing tellurium nanoribbons and their template reaction[J]. Crystengcomm,2012,14(1):251-255.
APA H. T. Zhu.,J. Luo.,H. Zhang.,J. K. Liang.,G. H. Rao.,...&Z. M. Du.(2012).Controlled hydrothermal synthesis of tri-wing tellurium nanoribbons and their template reaction.Crystengcomm,14(1),251-255.
MLA H. T. Zhu,et al."Controlled hydrothermal synthesis of tri-wing tellurium nanoribbons and their template reaction".Crystengcomm 14.1(2012):251-255.
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