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Modifications of the hydrotalcite film on AZ31 Mg alloy by phytic acid: The effects on morphology, composition and corrosion resistance
J. Chen; Y. W. Song; D. Y. Shan; E. H. Han
2013
发表期刊Corrosion Science
ISSN0010-938X
卷号74页码:130-138
摘要An environmentally friendly corrosion inhibitor phytic acid (PA) has been successfully added to modify the hydrotalcite (HT) film by adsorption and ion exchange approaches. In alkali PA solution, PO43- cannot substitute CO32- in the HT, but adsorb to the external surface; H2PO4-/HPO42- can insert into the HT after decarbonation under acidic condition. Partial decomposition occurs under both conditions. The PA/pH 11-HT film shows superior stability and lasting protective efficiency, and also can provide self-healing effect associated with the P adsorption in the filament. The worse resistance of the PA/pH 6.5-HT film may be related to the micro-cracks. (C) 2013 Elsevier Ltd. All rights reserved.
部门归属[chen, jun ; song, yingwei ; shan, dayong ; han, en-hou] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. ; song, yw (reprint author), chinese acad sci, inst met res, state key lab corros & protect, 62 wencui rd, shenyang 110016, peoples r china. ; ywsong@imr.ac.cn
关键词Magnesium Ir Spectroscopy Xrd Eis Repassivation Layered Double Hydroxides Conversion Coatings Magnesium Alloy Anion-exchange Intercalated Hydrotalcite Carbonate Ions Deintercalation Delamination Performance Compound
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/71153
专题中国科学院金属研究所
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J. Chen,Y. W. Song,D. Y. Shan,et al. Modifications of the hydrotalcite film on AZ31 Mg alloy by phytic acid: The effects on morphology, composition and corrosion resistance[J]. Corrosion Science,2013,74:130-138.
APA J. Chen,Y. W. Song,D. Y. Shan,&E. H. Han.(2013).Modifications of the hydrotalcite film on AZ31 Mg alloy by phytic acid: The effects on morphology, composition and corrosion resistance.Corrosion Science,74,130-138.
MLA J. Chen,et al."Modifications of the hydrotalcite film on AZ31 Mg alloy by phytic acid: The effects on morphology, composition and corrosion resistance".Corrosion Science 74(2013):130-138.
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