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Corrosion Inhibition of Mild Steel in Acidic Medium by Linseed Oil-Based Imidazoline
Y. Chen; Y. Y. Jiang; H. Chen; Z. Zhang; J. Q. Zhang; C. N. Cao
2013
发表期刊Journal of the American Oil Chemists Society
ISSN0003-021X
卷号90期号:9页码:1387-1395
摘要A new kind of corrosion inhibitor (LOBI) based on linseed oil has been synthesized. The molecular structure of LOBI was investigated using Fourier transform infrared spectroscopy and nuclear magnetic resonance spectrometer. Its inhibiting behavior on mild steel in 1.0 M HCl was studied by electrochemical potentiodynamic polarization, electrochemical impedance spectroscopy, scanning electron microscopy and X-ray photoelectron spectroscopy. Results reveal that LOBI was a good mixed-type inhibitor. The adsorption of LOBI at 40 A degrees C obeys the Langmuir adsorption isotherm. The N(1s) and S(2p) peaks of XPS measurement indicate that LOBI has been adsorbed onto a Q235 steel surface. The adsorption equilibrium constant, adsorption free energy and activation energy were also calculated, which indicated the adsorption of LOBI was chemisorption.
部门归属[chen, y. ; jiang, y. y. ; zhang, z. ; zhang, j. q. ; cao, c. n.] zhejiang univ, dept chem, hangzhou 310027, zhejiang, peoples r china. [chen, h.] cent south univ forestry & technol, coll mat sci & engn, changsha 410004, hunan, peoples r china. [zhang, j. q.] state key lab corros & protect met, shenyang 110016, peoples r china. ; zhang, z (reprint author), zhejiang univ, dept chem, hangzhou 310027, zhejiang, peoples r china. ; eaglezzy@zjuem.zju.edu.cn
关键词Acid Solutions Mild Steel Eis Acid Inhibition 1 m Hcl Sustainable Resource Hydrochloric-acid Derivatives Coatings Adsorption Iron
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/71166
专题中国科学院金属研究所
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GB/T 7714
Y. Chen,Y. Y. Jiang,H. Chen,et al. Corrosion Inhibition of Mild Steel in Acidic Medium by Linseed Oil-Based Imidazoline[J]. Journal of the American Oil Chemists Society,2013,90(9):1387-1395.
APA Y. Chen,Y. Y. Jiang,H. Chen,Z. Zhang,J. Q. Zhang,&C. N. Cao.(2013).Corrosion Inhibition of Mild Steel in Acidic Medium by Linseed Oil-Based Imidazoline.Journal of the American Oil Chemists Society,90(9),1387-1395.
MLA Y. Chen,et al."Corrosion Inhibition of Mild Steel in Acidic Medium by Linseed Oil-Based Imidazoline".Journal of the American Oil Chemists Society 90.9(2013):1387-1395.
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