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Reversible structural transformation of FeOx nanostructures on Pt under cycling redox conditions and its effect on oxidation catalysis
Q. Fu; Y. X. Yao; X. G. Guo; M. M. Wei; Y. X. Ning; H. Y. Liu; F. Yang; Z. Liu; X. H. Bao
2013
Source PublicationPhysical Chemistry Chemical Physics
ISSN1463-9076
Volume15Issue:35Pages:14708-14714
AbstractUnderstanding dynamic changes of catalytically active nanostructures under reaction conditions is a pivotal challenge in catalysis research, which has been extensively addressed in metal nanoparticles but is less explored in supported oxide nanocatalysts. Here, structural changes of iron oxide (FeOx) nanostructures supported on Pt in a gaseous environment were examined by scanning tunneling microscopy, ambient pressure X-ray photoelectron spectroscopy, and in situ X-ray absorption spectroscopy using both model systems and real catalysts. O-Fe (FeO) bilayer nanostructures can be stabilized on Pt surfaces in reductive environments such as vacuum conditions and H-2-rich reaction gas, which are highly active for low temperature CO oxidation. In contrast, exposure to H-2-free oxidative gases produces a less active O-Fe-O (FeO2) trilayer structure. Reversible transformation between the FeO bilayer and FeO2 trilayer structures can be achieved under alternating reduction and oxidation conditions, leading to oscillation in the catalytic oxidation performance.
description.department[fu, qiang ; yao, yunxi ; guo, xiaoguang ; wei, mingming ; ning, yanxiao ; liu, hongyang ; yang, fan ; bao, xinhe] chinese acad sci, dalian inst chem phys, state key lab catalysis, dalian 116023, peoples r china. [liu, hongyang] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. [liu, zhi] univ calif berkeley, lawrence berkeley natl lab, adv light source, berkeley, ca 94720 usa. ; fu, q (reprint author), chinese acad sci, dalian inst chem phys, state key lab catalysis, dalian 116023, peoples r china. ; qfu@dicp.ac.cn ; xhbao@dicp.ac.cn
KeywordTemperature Co Oxidation Oxide-films Photoelectron-spectroscopy Ferrous Centers Pt(111) Surface In-situ Nanoparticles Chemistry Au(111) Growth
URL查看原文
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/71219
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
Q. Fu,Y. X. Yao,X. G. Guo,et al. Reversible structural transformation of FeOx nanostructures on Pt under cycling redox conditions and its effect on oxidation catalysis[J]. Physical Chemistry Chemical Physics,2013,15(35):14708-14714.
APA Q. Fu.,Y. X. Yao.,X. G. Guo.,M. M. Wei.,Y. X. Ning.,...&X. H. Bao.(2013).Reversible structural transformation of FeOx nanostructures on Pt under cycling redox conditions and its effect on oxidation catalysis.Physical Chemistry Chemical Physics,15(35),14708-14714.
MLA Q. Fu,et al."Reversible structural transformation of FeOx nanostructures on Pt under cycling redox conditions and its effect on oxidation catalysis".Physical Chemistry Chemical Physics 15.35(2013):14708-14714.
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