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Polar Influence of the Organic Modifiers on the Structure of Montmorillonite in Epoxy Nanocomposites
F. C. Liu; E. H. Han; W. Ke; N. Tang; J. B. Wan; G. L. Yin; J. W. Deng; K. W. Zhao
2013
Source PublicationJournal of Materials Science & Technology
ISSN1005-0302
Volume29Issue:11Pages:1040-1046
AbstractThe epoxy nanocomposites with similar amines (CH3(CH2)(17)NH2 and CH3(CH2)(17)N(CH3)(3)Cl) treated montmorillonite clays have been investigated by wide- angle X- ray scattering, transmission electron microscopy (TEM), differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). Different nanocomposite structures, intercalation and exfoliation were formed by the reaction of octadecyltrimethylammonium chloride- exchanged and octadecylamine- exchanged clays with epoxy resin and phenalkamine as the curing agent, respectively. Results showed that the exfoliated nanocomposite can be obtained when octadecylamine with the lower polarity was used as a modifier. However, the intercalated nanocomposite can be obtained when octadecyltrimethylammonium chloride with higher polarity was used as a modifier.
description.department[liu, fu-chun ; han, en-hou ; ke, wei] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. [tang, nan ; wan, junbiao ; yin, guilai ; deng, jingwei ; zhao, kangwen] jiangxi elect power res inst, nanchang 330096, peoples r china. ; liu, fc (reprint author), chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. ; fcliu@imr.ac.cn
KeywordPolymer Clay Exfoliation Intercalation Clay Surface Modification Clay/epoxy Nanocomposites Mechanical-properties Corrosion Protection Curing Agents Slurry Method Carbon-steel Resin Dispersion Behavior
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Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/71358
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
F. C. Liu,E. H. Han,W. Ke,et al. Polar Influence of the Organic Modifiers on the Structure of Montmorillonite in Epoxy Nanocomposites[J]. Journal of Materials Science & Technology,2013,29(11):1040-1046.
APA F. C. Liu.,E. H. Han.,W. Ke.,N. Tang.,J. B. Wan.,...&K. W. Zhao.(2013).Polar Influence of the Organic Modifiers on the Structure of Montmorillonite in Epoxy Nanocomposites.Journal of Materials Science & Technology,29(11),1040-1046.
MLA F. C. Liu,et al."Polar Influence of the Organic Modifiers on the Structure of Montmorillonite in Epoxy Nanocomposites".Journal of Materials Science & Technology 29.11(2013):1040-1046.
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