On-line mass spectrometry study of electrochemical corrosion of the graphite electrode for vanadium redox flow battery

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	On-line mass spectrometry study of electrochemical corrosion of the graphite electrode for vanadium redox flow battery
	H. J. Liu; Q. Xu; C. W. Yan
	2013
发表期刊	Electrochemistry Communications
ISSN	1388-2481
卷号	28 页码:58-62
摘要	The electrochemical corrosion of the graphite electrode for vanadium redox flow battery is investigated by on-line mass spectrometry analysis. The results show that CO2 and CO form and evolve more preferably than O-2 on the graphite anode, which lead to the electrochemical corrosion of the graphite electrode. Furthermore, the evolution rate of O-2 is the highest one among evolved gases if the polarization potential becomes too positive. The oxidation of VO2+ on the graphite electrode in 2 M H2SO4 + 2 M VOSO4 hinders the carbon oxidation reaction and retards the electrochemical corrosion of the graphite electrode. (C) 2012 Elsevier B.V. All rights reserved.
部门归属	[liu, huijun ; xu, qian] northeastern univ, sch mat sci & met, shenyang 110819, peoples r china. [yan, chuanwei] chinese acad sci, state key lab corros & protect, inst met res, shenyang 110016, peoples r china. ; xu, q (reprint author), northeastern univ, sch mat sci & met, shenyang 110819, peoples r china. ; qianxu201@mail.neu.edu.cn
关键词	On-line Mass Spectrometry Graphite Electrode Electrochemical Corrosion Anodic Polarization Vanadium Redox Flow Battery Energy-storage Progress Cell
URL	查看原文
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/71366
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	H. J. Liu,Q. Xu,C. W. Yan. On-line mass spectrometry study of electrochemical corrosion of the graphite electrode for vanadium redox flow battery[J]. Electrochemistry Communications,2013,28:58-62.
APA	H. J. Liu,Q. Xu,&C. W. Yan.(2013).On-line mass spectrometry study of electrochemical corrosion of the graphite electrode for vanadium redox flow battery.Electrochemistry Communications,28,58-62.
MLA	H. J. Liu,et al."On-line mass spectrometry study of electrochemical corrosion of the graphite electrode for vanadium redox flow battery".Electrochemistry Communications 28(2013):58-62.