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Fabrication of transparent and luminescent CdTe/TiO2 hybrid film with enhanced photovoltaic property
W. Qi; Y. Z. Wang; Z. X. Yu; B. Li; L. X. Wu
2013
发表期刊Materials Letters
ISSN0167-577X
卷号107页码:60-63
摘要A novel strategy for fabricating surface modified quantum dots (QDs)/titania hybrid films with increased synergistic property is reported. Through electrostatic interaction, anionic CdTe QDs are enwrapped with a cationic surfactant bearing hydroxyl groups at hydrophobic terminal, forming a surfactant-encapsulated QD complex particle with hydroxyl active sites on its periphery. The complex is covalently doped into titania matrix by means of a sol-gel approach of tetraethyl orthotitanate. In comparison to the well designed materials with inorganic core and shell nanostructure, the present study utilizes the inorganic core but organic shell, which can further alloy to titiania supports evenly. The original luminescent property of QDs and the flexibility of titania sol-gel materials are well retained in the resulting hybrid films. The monodispersion of QDs in the matrices brings about high transparent titania films, leading to an enhanced photovoltaic effect and a visible region response for light excitation. (C) 2013 Elsevier B.V. All rights reserved.
部门归属[yu, zhenxiang] jilin univ, dept resp med, hosp 1, changchun 130023, peoples r china. [qi, wei ; wang, yizhan ; li, bao ; wu, lixin] jilin univ, state key lab supramol struct & mat, changchun 130012, peoples r china. [qi, wei] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; yu, zx (reprint author), jilin univ, dept resp med, hosp 1, changchun 130023, peoples r china. ; libao@jlu.edu.cn
关键词Quantum Dots Titania Hybrid Film Luminescence Photovoltaic Enhancement Mercapto-carboxylic-acids Nanocable Arrays Optical Gain Quantum Dots Nanocrystals Performance Cdse Nanocomposites Composites Cdte
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/71432
专题中国科学院金属研究所
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W. Qi,Y. Z. Wang,Z. X. Yu,et al. Fabrication of transparent and luminescent CdTe/TiO2 hybrid film with enhanced photovoltaic property[J]. Materials Letters,2013,107:60-63.
APA W. Qi,Y. Z. Wang,Z. X. Yu,B. Li,&L. X. Wu.(2013).Fabrication of transparent and luminescent CdTe/TiO2 hybrid film with enhanced photovoltaic property.Materials Letters,107,60-63.
MLA W. Qi,et al."Fabrication of transparent and luminescent CdTe/TiO2 hybrid film with enhanced photovoltaic property".Materials Letters 107(2013):60-63.
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