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A Novel Ion-exchange Method for the Synthesis of Nano-SnO/micro-C Hybrid Structure as High Capacity Anode Material in Lithium Ion Batteries
Z. Tan; Z. H. Sun; Q. Guo; H. H. Wang; D. S. Su
2013
发表期刊Journal of Materials Science & Technology
ISSN1005-0302
卷号29期号:7页码:609-612
摘要A novel and simple ion-exchange method was developed for the synthesis of nano-SnO/micro-C hybrid structure. The structure of the as prepared nano-SnO/micro-C was directly revealed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). SnO particles with the size about 25 nm were well confined in amorphous carbon microparticles. Carbon matrix in micrometer scale not only acts as a protective buffer for the SnO nanoparticles during the battery cycling processes, but also avoids the shortcomings of nanostructures, such as low tap density and potential safety threats. Electrochemical behaviors of the nano-SnO/micro-C were tested as anode material in lithium ion batteries. The initial reversible capacity is 508 mA h g(-1), and the reversible capacity after 60 cycles is 511 mA h g(-1), indicating good capacity retention ability.
部门归属[tan, zhi ; sun, zhenhua ; guo, qi ; wang, haihua ; su, dangsheng] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china. ; su, ds (reprint author), chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china. ; dangsheng@fhi-berlin.mpg.de
关键词Lithium Ion Battery Tin Oxide Nano-/micro Composites Irreversible Capacities Hollow Nanospheres Tin Performance Composites Carbons
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/71492
专题中国科学院金属研究所
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GB/T 7714
Z. Tan,Z. H. Sun,Q. Guo,et al. A Novel Ion-exchange Method for the Synthesis of Nano-SnO/micro-C Hybrid Structure as High Capacity Anode Material in Lithium Ion Batteries[J]. Journal of Materials Science & Technology,2013,29(7):609-612.
APA Z. Tan,Z. H. Sun,Q. Guo,H. H. Wang,&D. S. Su.(2013).A Novel Ion-exchange Method for the Synthesis of Nano-SnO/micro-C Hybrid Structure as High Capacity Anode Material in Lithium Ion Batteries.Journal of Materials Science & Technology,29(7),609-612.
MLA Z. Tan,et al."A Novel Ion-exchange Method for the Synthesis of Nano-SnO/micro-C Hybrid Structure as High Capacity Anode Material in Lithium Ion Batteries".Journal of Materials Science & Technology 29.7(2013):609-612.
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