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Supported carbon nanotubes on SiO2 spheres as robust monolithic catalysts for the oxidative dehydrogenation of ethylbenzene
H. Yuan; H. Y. Liu; J. Y. Diao; X. M. Gu; D. S. Su
2013
发表期刊New Carbon Materials
ISSN1007-8827
卷号28期号:5页码:336-341
摘要Novel carbon nanotube (CNT)/SiO2, monolithic catalysts for the oxidative dehydrogenation of ethylbenzene to styrene were synthesized by immobilizing CNTs onto commercial SiO, spheres. The CNTs completely cover the surface of the SiO2 spheres, and the catalysts exhibit an improved performance with a higher styrene yield and selectivity, and a higher ethylbenzene conversionthan commercial CNT powder. The catalysts also have a high mechanical strength and a diameter of 4 mm, which can decrease the pressure drop in the fixed bed reactor and also decrease the mass transfer resistance compared with a commercial CNT powder.
部门归属[yuan hua ; liu hong-yang ; diao jiang-yong ; gu xian-mo ; su dang-sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; su, ds (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; hyuan@imr.ac.cn ; dssu@imr.ac.cn
关键词Carbon Nanotubes Monoliths Ethylbenzene Dehydrogenation Heterogeneous Catalysis Chemical-vapor-deposition Heterogeneous Catalysis Nanofibers Nanocarbons Immobilization Purification Performance Foam
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/71657
专题中国科学院金属研究所
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H. Yuan,H. Y. Liu,J. Y. Diao,et al. Supported carbon nanotubes on SiO2 spheres as robust monolithic catalysts for the oxidative dehydrogenation of ethylbenzene[J]. New Carbon Materials,2013,28(5):336-341.
APA H. Yuan,H. Y. Liu,J. Y. Diao,X. M. Gu,&D. S. Su.(2013).Supported carbon nanotubes on SiO2 spheres as robust monolithic catalysts for the oxidative dehydrogenation of ethylbenzene.New Carbon Materials,28(5),336-341.
MLA H. Yuan,et al."Supported carbon nanotubes on SiO2 spheres as robust monolithic catalysts for the oxidative dehydrogenation of ethylbenzene".New Carbon Materials 28.5(2013):336-341.
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