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Reaction induced anomalous temperature dependence of equilibrium contact angle of TiZr based glass forming melt on Al2O3 substrate
B. Zhang; H. Li; Z. W. Zhu; H. M. Fu; A. M. Wang; C. Dong; H. F. Zhang; Z. Q. Hu
2013
Source PublicationMaterials Science and Technology
ISSN0267-0836
Volume29Issue:3Pages:332-336
AbstractThe wetting behaviours and interface reactions in Ti32.8Zr30.2Ni5.3Cu9Be22.7/Al2O3 system were investigated using a sessile drop technique at 1073-1223 K in high vacuum. Both the equilibrium contact angles and the interface reactions largely depend on the test temperature. The equilibrium contact angle first decreases and then increases with the increase in temperature. The minimum of the equilibrium contact angle is 21 degrees at 1143 K. The reason for the anomalous change of equilibrium contact angle is the change of the interface structure. At low temperature, the adsorption of alpha-Ti solid solution at the interface and the formation of Ti0.5Zr0.5O0.33 in the precursor film are beneficial to the wettability. With further increasing the temperature to 1173 K, the formation of ionic alpha-BeO is responsible for the deterioration in wettability.
description.department[zhang, b. ; li, h. ; zhu, z. w. ; fu, h. m. ; wang, a. m. ; zhang, h. f. ; hu, z. q.] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china. [zhang, b. ; dong, c.] dalian univ technol, sch mat sci & engn, dalian 116024, peoples r china. ; zhang, hf (reprint author), chinese acad sci, shenyang natl lab mat sci, inst met res, 72 wenhua rd, shenyang 110016, peoples r china. ; hfzhang@imr.ac.cn
KeywordWetting Behaviour Interface Reaction Tizr Based Bulk Metallic Glasses Al2o3 Substrate Bulk Metallic-glass Wetting Behavior System Wettability Solder
URL查看原文
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/71667
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
B. Zhang,H. Li,Z. W. Zhu,et al. Reaction induced anomalous temperature dependence of equilibrium contact angle of TiZr based glass forming melt on Al2O3 substrate[J]. Materials Science and Technology,2013,29(3):332-336.
APA B. Zhang.,H. Li.,Z. W. Zhu.,H. M. Fu.,A. M. Wang.,...&Z. Q. Hu.(2013).Reaction induced anomalous temperature dependence of equilibrium contact angle of TiZr based glass forming melt on Al2O3 substrate.Materials Science and Technology,29(3),332-336.
MLA B. Zhang,et al."Reaction induced anomalous temperature dependence of equilibrium contact angle of TiZr based glass forming melt on Al2O3 substrate".Materials Science and Technology 29.3(2013):332-336.
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