Towards low temperature thermal exfoliation of graphite oxide for graphene production | |
C. Zhang; W. Lv; X. Y. Xie; D. M. Tang; C. Liu; Q. H. Yang | |
2013 | |
Source Publication | Carbon
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ISSN | 0008-6223 |
Volume | 62Pages:11-24 |
Abstract | Realizing mass production of graphene materials at low cost and high quality is urgently required for their real applications. Thermal exfoliation of graphite oxide (GO) is considered as a promising strategy though it normally requires a high exfoliation temperature together with a fast heating rate, making the produced graphenes suffer from high cost and concentrated topological defects. A mild exfoliation of GO at a far lower temperature than the predicted minimum temperature, has been demonstrated by introducing a high vacuum to exert an outward drawing force which helps effective exfoliation of the stacked graphene layers. In this contribution, together with a discussion on the foundation of thermal exfoliation and the general principle for low-temperature exfoliation, we review current strategies and indicate possible novel approaches. Low cost and easy operability are highlighted for the low-temperature exfoliation and the resulting graphene materials are characterized by low defect concentration, and unique and tunable surface chemistry to promote potential mass applications in energy-related areas. (c) 2013 Elsevier Ltd. All rights reserved. |
description.department | [zhang, chen ; lv, wei ; xie, xiaoying ; yang, quan-hong] tianjin univ, sch chem engn & technol, tianjin 300072, peoples r china. [lv, wei ; yang, quan-hong] tsinghua univ, grad sch shenzhen, engn lab functionalized carbon mat, shenzhen 518055, peoples r china. [tang, daiming ; liu, chang] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; yang, qh (reprint author), tianjin univ, sch chem engn & technol, tianjin 300072, peoples r china. ; yang.quanhong@sz.tsinghua.edu.cn |
Keyword | Lithium-ion Batteries Electrical-conductivity Functionalized Graphene High-quality Reduction Nanosheets Sheets Films Performance Ultracapacitors |
URL | 查看原文 |
Language | 英语 |
Document Type | 期刊论文 |
Identifier | http://ir.imr.ac.cn/handle/321006/71673 |
Collection | 中国科学院金属研究所 |
Recommended Citation GB/T 7714 | C. Zhang,W. Lv,X. Y. Xie,et al. Towards low temperature thermal exfoliation of graphite oxide for graphene production[J]. Carbon,2013,62:11-24. |
APA | C. Zhang,W. Lv,X. Y. Xie,D. M. Tang,C. Liu,&Q. H. Yang.(2013).Towards low temperature thermal exfoliation of graphite oxide for graphene production.Carbon,62,11-24. |
MLA | C. Zhang,et al."Towards low temperature thermal exfoliation of graphite oxide for graphene production".Carbon 62(2013):11-24. |
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