Z-Average Radius of Gyration of Polymers in the Ternary Self-Condensing Vinyl Polymerization System with Unequal Reactivity

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	Z-Average Radius of Gyration of Polymers in the Ternary Self-Condensing Vinyl Polymerization System with Unequal Reactivity
	X. Z. Hong; F. Gu; H. J. Wang; X. W. Ba
	2013
发表期刊	Chemical Journal of Chinese Universities-Chinese
ISSN	0251-0790
卷号	34 期号:9 页码:2223-2227
摘要	The Z-average radius of gyration of hyperbranched polymers formed in the ternary self-condensing vinyl polymerization system was studied by the method of Monte Carlo simulation, in which the unequal reactivity was taken into account. As a result, the effects of the reactivity difference in two types of active centers, the molar ratio of inimers to monomers, the molar ratio and functionality of core initiators were discussed. It is found that these factors can give rise to a significant influence on the Z-average radii of gyration of hyperbranched polymers with and without the core initiator. This provides some useful clues for regulating the dimension and structure of the hyperbranched polymers in the relevant experiments.
部门归属	[hong xiao-zhong] hebei univ, coll phys sci & technol, baoding 071002, peoples r china. [gu fang ; wang hai-jun ; ba xin-wu] hebei univ, coll chem & environm sci, baoding 071002, peoples r china. [wang hai-jun] hebei univ, chem biol key lab hebei prov, baoding 071002, peoples r china. [wang hai-jun] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china. ; wang, hj (reprint author), hebei univ, coll phys sci & technol, baoding 071002, peoples r china. ; whj@mail.hbu.cn
关键词	Self-condensing Vinyl Polymerization Unequal Reactivity Z-average Radius Of Gyration Monte Carlo Simulation Molecular-weight Distribution Monte-carlo-simulation Multifunctional Core Molecules Equal Rate Constants Hyperbranched Polymers Tetrafunctional Initiator Radical Polymerization Copolymerization Parameters Kinetics
URL	查看原文
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/72435
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	X. Z. Hong,F. Gu,H. J. Wang,et al. Z-Average Radius of Gyration of Polymers in the Ternary Self-Condensing Vinyl Polymerization System with Unequal Reactivity[J]. Chemical Journal of Chinese Universities-Chinese,2013,34(9):2223-2227.
APA	X. Z. Hong,F. Gu,H. J. Wang,&X. W. Ba.(2013).Z-Average Radius of Gyration of Polymers in the Ternary Self-Condensing Vinyl Polymerization System with Unequal Reactivity.Chemical Journal of Chinese Universities-Chinese,34(9),2223-2227.
MLA	X. Z. Hong,et al."Z-Average Radius of Gyration of Polymers in the Ternary Self-Condensing Vinyl Polymerization System with Unequal Reactivity".Chemical Journal of Chinese Universities-Chinese 34.9(2013):2223-2227.