Effect of Ti on the microstructure and Al-water reactivity of Al-rich alloy | |
T. T. He; W. Wang; D. M. Chen; K. Yang | |
2014 | |
发表期刊 | International Journal of Hydrogen Energy
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ISSN | 0360-3199 |
卷号 | 39期号:2页码:684-691 |
摘要 | Ti-bearing Al alloys (0.1-1 wt.%) were prepared using arc melting techniques. Their microstructures were investigated using XRD and SEM/EDX, and found to depend strongly on Ti contents. Al grains are columnar as Ti contents are lower, but they are refined and turn into equiaxed ones when Ti contents are higher. The particle sizes of Ga-In-Sn phase decrease with Al grain refinement. Al-water reactivities were also investigated under different water temperatures. Kinetic measurements found that Ti prohibits Al-water reaction and reduces hydrogen yields when alloys contain little Ti. However, Al reacts with water fast and hydrogen yields rise with the increase of Ti contents of alloys. Reasons concerning the variations of microstructures and Al-water reactivities with Ti additions are discussed. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
部门归属 | [he, t. t. ; wang, w. ; chen, d. m. ; yang, k.] chinese acad sci, inst met res, shenyang 110016, peoples r china. ; wang, w (reprint author), chinese acad sci, inst met res, shenyang 110016, peoples r china. ; wei.wang@imr.ac.cn ; demin.chen.1@imr.ac.cn |
关键词 | Ti addiTion Al Alloy Microstructure Reactivity Hydrogen Generation Rate Hydrogen-generation Aluminum-alloys Grain-refinement Fuel-cells Hydrolysis Activation Mechanism Metal |
URL | 查看原文 |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/72546 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | T. T. He,W. Wang,D. M. Chen,et al. Effect of Ti on the microstructure and Al-water reactivity of Al-rich alloy[J]. International Journal of Hydrogen Energy,2014,39(2):684-691. |
APA | T. T. He,W. Wang,D. M. Chen,&K. Yang.(2014).Effect of Ti on the microstructure and Al-water reactivity of Al-rich alloy.International Journal of Hydrogen Energy,39(2),684-691. |
MLA | T. T. He,et al."Effect of Ti on the microstructure and Al-water reactivity of Al-rich alloy".International Journal of Hydrogen Energy 39.2(2014):684-691. |
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