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Effect of Ti on the microstructure and Al-water reactivity of Al-rich alloy
T. T. He; W. Wang; D. M. Chen; K. Yang
2014
发表期刊International Journal of Hydrogen Energy
ISSN0360-3199
卷号39期号:2页码:684-691
摘要Ti-bearing Al alloys (0.1-1 wt.%) were prepared using arc melting techniques. Their microstructures were investigated using XRD and SEM/EDX, and found to depend strongly on Ti contents. Al grains are columnar as Ti contents are lower, but they are refined and turn into equiaxed ones when Ti contents are higher. The particle sizes of Ga-In-Sn phase decrease with Al grain refinement. Al-water reactivities were also investigated under different water temperatures. Kinetic measurements found that Ti prohibits Al-water reaction and reduces hydrogen yields when alloys contain little Ti. However, Al reacts with water fast and hydrogen yields rise with the increase of Ti contents of alloys. Reasons concerning the variations of microstructures and Al-water reactivities with Ti additions are discussed. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
部门归属[he, t. t. ; wang, w. ; chen, d. m. ; yang, k.] chinese acad sci, inst met res, shenyang 110016, peoples r china. ; wang, w (reprint author), chinese acad sci, inst met res, shenyang 110016, peoples r china. ; wei.wang@imr.ac.cn ; demin.chen.1@imr.ac.cn
关键词Ti addiTion Al Alloy Microstructure Reactivity Hydrogen Generation Rate Hydrogen-generation Aluminum-alloys Grain-refinement Fuel-cells Hydrolysis Activation Mechanism Metal
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/72546
专题中国科学院金属研究所
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GB/T 7714
T. T. He,W. Wang,D. M. Chen,et al. Effect of Ti on the microstructure and Al-water reactivity of Al-rich alloy[J]. International Journal of Hydrogen Energy,2014,39(2):684-691.
APA T. T. He,W. Wang,D. M. Chen,&K. Yang.(2014).Effect of Ti on the microstructure and Al-water reactivity of Al-rich alloy.International Journal of Hydrogen Energy,39(2),684-691.
MLA T. T. He,et al."Effect of Ti on the microstructure and Al-water reactivity of Al-rich alloy".International Journal of Hydrogen Energy 39.2(2014):684-691.
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