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Creation of Bronsted acid sites on Sn-based solid catalysts for the conversion of biomass
L. Wang; J. Zhang; X. F. Wang; B. S. Zhang; W. J. Ji; X. J. Meng; J. X. Li; D. S. Su; X. H. Bao; F. S. Xiao
2014
发表期刊Journal of Materials Chemistry A
ISSN2050-7488
卷号2期号:11页码:3725-3729
摘要Hydroxyl-attached Sn species are highly dispersed on the surface of mesoporous silica (SBA-15) by the grafting of dimethyldichlorostannane followed by calcination to transform the methyl groups into hydroxyl groups (S-Sn-OH). S-Sn-OH has both Lewis and Bronsted acidic sites, resulting in superior catalytic activities in the acetalisation of glycerol.
部门归属[wang, liang ; zhang, jian ; meng, xiangju ; xiao, feng-shou] zhejiang univ, key lab appl chem zhejiang prov, hangzhou 310028, peoples r china. [wang, xuefeng ; bao, xinhe] chinese acad sci, dalian inst chem phys, state key lab catalysis, dalian 116023, peoples r china. [su, dang sheng] max planck gesell, dept inorgan chem, fritz haber inst, d-14195 berlin, germany. [zhang, bingsen ; su, dang sheng] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china. [ji, weijie] nanjing univ, key lab mesoscop chem, moe, dept chem, nanjing 210093, jiangsu, peoples r china. [li, jixue] zhejiang univ, dept mat sci & engn, hangzhou 310028, peoples r china. [wang, xuefeng] dalian univ, sch environm & chem engeering, dalian 116622, peoples r china. ; xiao, fs (reprint author), zhejiang univ, key lab appl chem zhejiang prov, hangzhou 310028, peoples r china. ; dangsheng@fhi-berlin.mpg.de ; xhbao@dicp.ac.cn ; fsxiao@zju.edu.cn
关键词Sba-15 Mesoporous Materials Supported Metal-clusters Molecular-sieves Zeolite Catalyst Aqueous-media Lactic-acid Lewis Glycerol Water Fructose
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/72584
专题中国科学院金属研究所
推荐引用方式
GB/T 7714
L. Wang,J. Zhang,X. F. Wang,et al. Creation of Bronsted acid sites on Sn-based solid catalysts for the conversion of biomass[J]. Journal of Materials Chemistry A,2014,2(11):3725-3729.
APA L. Wang.,J. Zhang.,X. F. Wang.,B. S. Zhang.,W. J. Ji.,...&F. S. Xiao.(2014).Creation of Bronsted acid sites on Sn-based solid catalysts for the conversion of biomass.Journal of Materials Chemistry A,2(11),3725-3729.
MLA L. Wang,et al."Creation of Bronsted acid sites on Sn-based solid catalysts for the conversion of biomass".Journal of Materials Chemistry A 2.11(2014):3725-3729.
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