Water Uptake of a Sandwich-Structured Composite Film Coated on a Mg-Gd-Y Alloy: Experiments and Model Validation

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	Water Uptake of a Sandwich-Structured Composite Film Coated on a Mg-Gd-Y Alloy: Experiments and Model Validation
	X. H. Guo; K. Q. Du; Q. Z. Guo; H. Ge; Y. Wang; R. Wang; F. H. Wang
	2014
发表期刊	Journal of the Electrochemical Society
ISSN	0013-4651
卷号	161 期号:4 页码:C188-C194
摘要	Water diffusion in a sandwich-structured composite film on a Mg-Gd-Y alloy was experimentally investigated using electrochemical impedance spectroscopy (EIS). The composite film contained an inner integration layer and an outer fluorocarbon (FC) layer. The integration layer was prepared by depositing an environment-friendly self-assembled nanoparticle film on the surface of a plasma electrolytic oxidation film. The resulting structure is therefore referred to as PSF. The measured value of the diffusion coefficient of the PSF film by the EIS method was compared to the value predicted using a mathematical model. The noncontinuity of the water concentration at the interface of the integration and FC layers resulted in a significant difference between the diffusion coefficients obtained by the experimental EIS method and mathematical model. A coefficient "k(e)" was introduced to the Fick's first law of diffusion, and a PSF model validation was used to confirm the concentration jump on the FC-integration boundary of the PSF film. When k(e) << 1, the calculated diffusion coefficient (D-eff(M)) of the PSF film by the mathematical model was found similar to that obtained by the EIS experimental method. (C) 2014 The Electrochemical Society. All rights reserved.
部门归属	[guo, xinghua ; du, keqin ; guo, quanzhong ; wang, yong ; wang, fuhui] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. [ge, hao] liaoning univ, coll chem, liaoning key lab green synth & preparat chem adv, shenyang 110036, peoples r china. [wang, rong] ningbo branch ordnance sci china, ningbo, zhejiang, peoples r china. ; guo, xh (reprint author), chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. ; kqdu@imr.ac.cn
关键词	Electrochemical Impedance Spectroscopy Different Paint Systems Barrier Properties Ftir-atr Silicate Nanocomposites Corrosion Protection Nafion Membranes Organic Coatings Magnesium Alloy Polymer-films
URL	查看原文
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/72850
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	X. H. Guo,K. Q. Du,Q. Z. Guo,et al. Water Uptake of a Sandwich-Structured Composite Film Coated on a Mg-Gd-Y Alloy: Experiments and Model Validation[J]. Journal of the Electrochemical Society,2014,161(4):C188-C194.
APA	X. H. Guo.,K. Q. Du.,Q. Z. Guo.,H. Ge.,Y. Wang.,...&F. H. Wang.(2014).Water Uptake of a Sandwich-Structured Composite Film Coated on a Mg-Gd-Y Alloy: Experiments and Model Validation.Journal of the Electrochemical Society,161(4),C188-C194.
MLA	X. H. Guo,et al."Water Uptake of a Sandwich-Structured Composite Film Coated on a Mg-Gd-Y Alloy: Experiments and Model Validation".Journal of the Electrochemical Society 161.4(2014):C188-C194.