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Cerium cinnamate as an environmentally benign inhibitor pigment for epoxy coatings on AA 2024-T3
H. W. Shi; E. H. Han; S. V. Lamaka; M. L. Zheludkevich; F. C. Liu; M. G. S. Ferreira
2014
发表期刊Progress in Organic Coatings
ISSN0300-9440
卷号77期号:4页码:765-773
摘要An environmentally friendly inhibitor, cerium cinnamate (CeCin), was studied as an additive to an epoxy coating. The effects of corrosion inhibition on AA 2024-T3 provided by cerium cation and cinnamate anion were investigated by electrochemistry impedance spectra (EIS) and polarization tests. It was found that cerium ion and cinnamate group have synergistic inhibiting effects. The EIS results show that CeCin is an effective inhibitor pigment for improving the corrosion resistance of epoxy coatings on AA2024-T3, as reflected by the much higher coating resistance than that of the blank epoxy coating. The inhibiting effect of CeCin during the onset of corrosion in defects of the epoxy coating was verified using scanning vibrating electrode technique (SVET), which is in agreement with the EIS results. (C) 2014 Elsevier B.V. All rights reserved.
部门归属[shi, hongwei ; han, en-hou ; liu, fuchun] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. [lamaka, s. v. ; ferreira, m. g. s.] univ tecn lisboa, inst super tecn, icems, p-1049001 lisbon, portugal. [zheludkevich, m. l. ; ferreira, m. g. s.] univ aveiro, dept mat & ceram engn, ciceco, p-3810193 aveiro, portugal. ; shi, hw (reprint author), chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. ; hwshi@imr.ac.cn
关键词Aa 2024-t3 Organic Coatings Xps Eis Corrosion Active Corrosion Protection Oxide Conversion Coatings Aluminum-alloy Corrosion Sol-gel Coatings Chromate Aa2024 Steel Spectroscopy Passivation Mechanisms
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/72903
专题中国科学院金属研究所
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H. W. Shi,E. H. Han,S. V. Lamaka,et al. Cerium cinnamate as an environmentally benign inhibitor pigment for epoxy coatings on AA 2024-T3[J]. Progress in Organic Coatings,2014,77(4):765-773.
APA H. W. Shi,E. H. Han,S. V. Lamaka,M. L. Zheludkevich,F. C. Liu,&M. G. S. Ferreira.(2014).Cerium cinnamate as an environmentally benign inhibitor pigment for epoxy coatings on AA 2024-T3.Progress in Organic Coatings,77(4),765-773.
MLA H. W. Shi,et al."Cerium cinnamate as an environmentally benign inhibitor pigment for epoxy coatings on AA 2024-T3".Progress in Organic Coatings 77.4(2014):765-773.
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