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A novel mechanism for the oxidation reaction of VO2+ on a graphite electrode in acidic solutions
W. J. Wang; X. Z. Fan; J. G. Liu; C. W. Yan; C. L. Zeng
2014
Source PublicationJournal of Power Sources
ISSN0378-7753
Volume261Pages:212-220
AbstractWith the consideration of optimizing the performance of the all-vanadium redox flow battery (VRB), the oxidation reaction mechanism of VO2+ on a rotating graphite disk electrode has been investigated by potentiodynamic polarization in sulfuric acid solutions with various pH and vanadium concentrations. Furthermore, the reaction orders of VO2+ and H+ for the oxidation reaction of VO2+ have been calculated from the polarization results and compared with the theoretical results according to the possible reaction mechanisms available in the literature. However, a new oxidation reaction mechanism has been proposed to describe the oxidation of VO2+ at last, and the theoretic reaction orders of VO2+ and H+ based on the new mechanism are consistent with the experimental results when the electrochemical reaction is the rate-limited process. Moreover, a corresponding kinetic equation has been established for the oxidation reaction of VO2+ on a spectroscopically pure graphite electrode, and can be well used to predict the polarization behavior in V (IV) acidic solutions. (c) 2014 Elsevier B.V. All rights reserved.
description.department[wang, wenjun ; fan, xinzhuang ; liu, jianguo ; yan, chuanwei ; zeng, chaoliu] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. ; fan, xz (reprint author), chinese acad sci, inst met res, state key lab corros & protect, 62 wencui rd, shenyang 110016, peoples r china. ; xzfan@imr.ac.cn
KeywordVanadium Reaction Mechanism Kinetic Equation Rotating Disk System Carbon Electrodes Redox Flow Batteries Solid-state Spectroscopy v(Iv)/v(v) Complexes Ions Cell
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Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/72922
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
W. J. Wang,X. Z. Fan,J. G. Liu,et al. A novel mechanism for the oxidation reaction of VO2+ on a graphite electrode in acidic solutions[J]. Journal of Power Sources,2014,261:212-220.
APA W. J. Wang,X. Z. Fan,J. G. Liu,C. W. Yan,&C. L. Zeng.(2014).A novel mechanism for the oxidation reaction of VO2+ on a graphite electrode in acidic solutions.Journal of Power Sources,261,212-220.
MLA W. J. Wang,et al."A novel mechanism for the oxidation reaction of VO2+ on a graphite electrode in acidic solutions".Journal of Power Sources 261(2014):212-220.
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