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Influences of the main anodic electroplating parameters on cerium oxide films
Y. Yang; Y. M. Yang; X. Q. Du; Y. Chen; Z. Zhang; J. Q. Zhang
2014
Source PublicationApplied Surface Science
ISSN0169-4332
Volume305Pages:330-336
AbstractCerium oxide thin films were fabricated onto 316 L stainless steel via a potentiostatically anodic electrodeposition approach in the solutions containing cerium(III) nitrate (0.05 M), ammonia acetate (0.1 M) and ethanol (10% V/V). The electrochemical behaviors and deposition parameters (applied potential, bath temperature, dissolving 02 and bath pH) have been investigated. Results show that, the electrochemical oxidation of Ce3+ goes through one electrochemical step, which is under charge transfer control. The optimum applied potential for film deposition is 0.8 V. Bath temperature plays a significant effect on the deposition rate, composition (different colors of the film) and surface morphology of the deposits. Due to the hydrolysis of Ce3+, cerous hydroxide is facility to form when the bath temperature is higher than 60 C. The electroplating bath pH is another key role for the anodic deposition of cerium oxide thin films, and the best bath pH is around 6.20. N-2 or O-2 purged into the bath will result in film porosities and O-2 favors cerium oxide particles and film generation. (c) 2014 Elsevier B.V. All rights reserved.
description.department[yang, yang ; yang, yumeng ; du, xiaoqing ; chen, yu ; zhang, zhao ; zhang, jianqing] zhejiang univ, dept chem, hangzhou 310027, zhejiang, peoples r china. [zhang, jianqing] state key lab corros & protect met, shenyang 110016, peoples r china. ; zhang, z (reprint author), zhejiang univ, dept chem, hangzhou 310027, zhejiang, peoples r china. ; eaglezzy@zjuem.zju.edu.cn
KeywordCerium Oxides Thin Films Anodic Electrodeposition Thin-films Cathodic Electrodeposition Hydrothermal Synthesis Galvanized Steel Silane Films Doped Ceria Ceo2 Powders Nanoparticles Deposition
URL查看原文
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/72954
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
Y. Yang,Y. M. Yang,X. Q. Du,et al. Influences of the main anodic electroplating parameters on cerium oxide films[J]. Applied Surface Science,2014,305:330-336.
APA Y. Yang,Y. M. Yang,X. Q. Du,Y. Chen,Z. Zhang,&J. Q. Zhang.(2014).Influences of the main anodic electroplating parameters on cerium oxide films.Applied Surface Science,305,330-336.
MLA Y. Yang,et al."Influences of the main anodic electroplating parameters on cerium oxide films".Applied Surface Science 305(2014):330-336.
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