Electrochemical investigation of microporous and mesoporous alpha-Fe2O3 particles for lithium-ion batteries | |
N. Zheng; Y. X. Chen; X. B. Deng; Z. Q. Liu; H. B. Liu | |
2014 | |
发表期刊 | Materials Letters
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ISSN | 0167-577X |
卷号 | 124页码:4-7 |
摘要 | alpha-Fe2O3 has been regarded as a promising candidate as anode materials for high energy-density lithium-ion batteries, because of its high capacity, low cost and environmental affinity. A facile hydrothermal route has been developed to synthesize monocrystalline microporous and mesoporous alpha-Fe2O3 particles by using anions Cl- and F- as pore-formation additives in precursor solution, respectively. Electrochemical investigation indicates that the mesoporous alpha-Fe2O3 particles display higher cyclic stabilities and capacity retentions than the microporous alpha-Fe2O3 particles at different current densities, although their sizes are in micrometer range, which indicate that the mesoporous alpha-Fe2O3 particles are promising anode candidate for high energy-density lithium-ion batteries. Furthermore, this facile hydrothermal route using anion Cl- or F- as pore-formation additives may be extended to synthesis of other porous metal oxides. (C) 2014 Elsevier B.V. All rights reserved. |
部门归属 | [zheng, na ; chen, yuxi ; deng, xiaobin ; liu, hongbo] hunan univ, coll mat & engn, changsha 410082, hunan, peoples r china. [liu, zhi-quan] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; chen, yx (reprint author), hunan univ, coll mat & engn, changsha 410082, hunan, peoples r china. ; yxchen@hnu.edu.cn |
关键词 | Energy Storage And Conversion Lithium Ion Batteries Iron Oxide Hydrothermal Process Electron Microscopy Negative-electrode Nanoparticles Performance Hematite Carbon Li |
URL | 查看原文 |
语种 | 英语 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/72979 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | N. Zheng,Y. X. Chen,X. B. Deng,et al. Electrochemical investigation of microporous and mesoporous alpha-Fe2O3 particles for lithium-ion batteries[J]. Materials Letters,2014,124:4-7. |
APA | N. Zheng,Y. X. Chen,X. B. Deng,Z. Q. Liu,&H. B. Liu.(2014).Electrochemical investigation of microporous and mesoporous alpha-Fe2O3 particles for lithium-ion batteries.Materials Letters,124,4-7. |
MLA | N. Zheng,et al."Electrochemical investigation of microporous and mesoporous alpha-Fe2O3 particles for lithium-ion batteries".Materials Letters 124(2014):4-7. |
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