Efficient Hydrogenation of Alkyl Formate to Methanol over Nanocomposite Copper/Alumina Catalysts

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	Efficient Hydrogenation of Alkyl Formate to Methanol over Nanocomposite Copper/Alumina Catalysts
	X. L. Du; X. P. Sun; C. Jin; Z. Jiang; D. S. Su; J. Q. Wang
	2014
发表期刊	Chemcatchem
ISSN	1867-3880
卷号	6 期号:11 页码:3075-3079
摘要	The production of methanol, an important fuel and chemical feedstock, from carbon dioxide is an important process for CO2 utilization. We describe herein a mild and efficient method for the indirect hydrogenation of carbon dioxide to methanol via a CO2-derived formate ester intermediate by using a simple heterogeneous catalyst system comprising Cu highly dispersed in an alumina matrix under solvent-free conditions. This catalyst is also effective for the hydrogenation of other formate esters, such as ethyl formate, propyl formate, and butyl formate.
部门归属	[du, xian-long ; sun, xue-ping ; jin, chan ; jiang, zheng ; wang, jian-qiang] chinese acad sci, shanghai inst appl phys, key lab interfacial phys & technol, shanghai 201800, peoples r china. [su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; su, ds (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, wenhua rd 72, shenyang 110016, peoples r china. ; dssu@imr.ac.cn ; wangjianqiang@sinap.ac.cn
关键词	Carbon Dioxide Copper Formate Esters Hydrogenation Methanol Carbon-dioxide Hydrogenation Methyl Formate Cu/zn/al/zr Catalysts Co2 Hydrogenation Formic-acid Hydrogenolysis Performance Precursors Conversion Gas
URL	查看原文
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/73219
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	X. L. Du,X. P. Sun,C. Jin,et al. Efficient Hydrogenation of Alkyl Formate to Methanol over Nanocomposite Copper/Alumina Catalysts[J]. Chemcatchem,2014,6(11):3075-3079.
APA	X. L. Du,X. P. Sun,C. Jin,Z. Jiang,D. S. Su,&J. Q. Wang.(2014).Efficient Hydrogenation of Alkyl Formate to Methanol over Nanocomposite Copper/Alumina Catalysts.Chemcatchem,6(11),3075-3079.
MLA	X. L. Du,et al."Efficient Hydrogenation of Alkyl Formate to Methanol over Nanocomposite Copper/Alumina Catalysts".Chemcatchem 6.11(2014):3075-3079.