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High-performance nickel-platinum nanocatalyst supported on mesoporous alumina for hydrogen generation from hydrous hydrazine
Y. Y. Jiang; Q. Kang; J. J. Zhang; H. B. Dai; P. Wang
2015
发表期刊Journal of Power Sources
ISSN0378-7753
卷号273页码:554-560
摘要The catalyst with high activity, 100% selectivity and good durability is highly desirable in developing a hydrous hydrazine-based hydrogen generation system. Herein we report the synthesis of nickel-platinum (Ni-Pt) bimetallic nanoparticles supported on mesoporous alumina (MA) using a simple one-pot evaporation-induced self-assembly method. The Ni-Pt/MA catalyst exhibits excellent activity and satisfactory stability for selectively catalyzing the decomposition of hydrous hydrazine to generate hydrogen at mild temperatures, which compares favorably with the performance of the catalysts developed to date. The facile synthesis of high-performance and cost-effective Ni-based catalyst is of clear significance for the development of hydrous hydrazine as a viable hydrogen carrier. (C) 2014 Elsevier B.V. All rights reserved.
部门归属[jiang, yuanyuan ; zhang, jingjing ; dai, hong-bin ; wang, ping] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. [kang, qiang] chinese acad sci, inst met res, anal & testing div, shenyang 110016, peoples r china. ; dai, hb (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china. ; hbdai@imr.ac.cn ; pingwang@imr.ac.cn
关键词Decomposition Hydrogen Generation Hydrous Hydrazine Mesoporous Alumina Nickel-platinum Alloy Nanocatalyst Room-temperature Efficient Catalyst Storage Decomposition N2h4-center-dot-h2o Rhodium
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/73254
专题中国科学院金属研究所
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Y. Y. Jiang,Q. Kang,J. J. Zhang,et al. High-performance nickel-platinum nanocatalyst supported on mesoporous alumina for hydrogen generation from hydrous hydrazine[J]. Journal of Power Sources,2015,273:554-560.
APA Y. Y. Jiang,Q. Kang,J. J. Zhang,H. B. Dai,&P. Wang.(2015).High-performance nickel-platinum nanocatalyst supported on mesoporous alumina for hydrogen generation from hydrous hydrazine.Journal of Power Sources,273,554-560.
MLA Y. Y. Jiang,et al."High-performance nickel-platinum nanocatalyst supported on mesoporous alumina for hydrogen generation from hydrous hydrazine".Journal of Power Sources 273(2015):554-560.
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