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Palladium Nanoparticles Embedded in the Inner Surfaces of Carbon Nanotubes: Synthesis, Catalytic Activity, and Sinter Resistance
H. Y. Liu; L. Y. Zhang; N. Wang; D. S. Su
2014
发表期刊Angewandte Chemie-International Edition
ISSN1433-7851
卷号53期号:46页码:12634-12638
摘要The highly efficient preparation of metal nanoparticles embedded in a carbon nanotube remains a considerable challenge. Herein, we report a simple and template-based procedure for the fabrication of carbon nanotubes with Pd nanoparticles uniformly embedded in the inner carbon surfaces. In addition to the novel structure, the sinter-resistance of the as-prepared Pd/C nanocomposite was much better than that of the traditional carbon-nanotube-supported Pd catalysts. The as-prepared Pd/C nanocomposite has a high recyclability in a liquid-phase Suzuki coupling reaction. This strategy may be extended as a general approach to prepare metal nanoparticles supported on carbon-nanotubes.
部门归属[liu, hongyang ; zhang, liyun ; su, dang sheng] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china. [wang, ning] hong kong univ sci & technol, dept phys, hong kong, hong kong, peoples r china. ; su, ds (reprint author), chinese acad sci, shenyang natl lab mat sci, inst met res, 72 wenhua rd, shenyang 110016, peoples r china. ; dssu@imr.ac.cn
关键词Carbon Nanotubes Heterogeneous Catalysis Nanoparticles Palladium Sinter Resistance Oxygen Reduction Reaction Coupling Reactions Particles Nanocomposites Performance Nanofibers Nanobelts
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/73302
专题中国科学院金属研究所
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H. Y. Liu,L. Y. Zhang,N. Wang,et al. Palladium Nanoparticles Embedded in the Inner Surfaces of Carbon Nanotubes: Synthesis, Catalytic Activity, and Sinter Resistance[J]. Angewandte Chemie-International Edition,2014,53(46):12634-12638.
APA H. Y. Liu,L. Y. Zhang,N. Wang,&D. S. Su.(2014).Palladium Nanoparticles Embedded in the Inner Surfaces of Carbon Nanotubes: Synthesis, Catalytic Activity, and Sinter Resistance.Angewandte Chemie-International Edition,53(46),12634-12638.
MLA H. Y. Liu,et al."Palladium Nanoparticles Embedded in the Inner Surfaces of Carbon Nanotubes: Synthesis, Catalytic Activity, and Sinter Resistance".Angewandte Chemie-International Edition 53.46(2014):12634-12638.
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