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Fabrication of a large-area, flexible and color-neutral single-wall carbon nanotube:sodium dodecylbenzene sulfonate/poly-(3,4-ethylenedioxythiophene): poly(4-styrenesulfonate) transparent conductive film having a new conduction mechanism
W. B. Liu; J. H. Du; L. P. Ma; H. F. Zhu; H. M. Cheng
2014
发表期刊Carbon
ISSN0008-6223
卷号80页码:112-119
摘要Flexible transparent conductive films (TCFs) are vital to promote the development of flexible and foldable devices including touch panels, displays, organic solar cells, etc. We have prepared a large-area, flexible, and color-neutral single-wall carbon nanotube:sodium dodecylbenzene sulfonate/poly-(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (SWCNT:SDBS/PEDOT:PSS) composite TCF on a poly(ethylene terephthalate) substrate by a spray coating method. The TCF has a sheet resistance of 178 Omega sq(-1) with 85% transmittance at 550 nm. The light transmission characteristics of the films can be tuned by changing the mass fraction of SWCNTs. When the mass fraction of SWCNTs is higher than 4 wt.%, the original blue tint of the TCFs has disappeared. More importantly, we find that SDBS may play a more important role than the SWCNT network in improving the electrical conductivity of the films by acting as a secondary dopant of PEDOT:PSS, which is different from the traditional understanding and existing explanation about the conduction mechanism of PEDOT:PSS-based composite films. (C) 2014 Elsevier Ltd. All rights reserved.
部门归属[liu, wen-bin ; du, jinhong ; ma, lai-peng ; zhu, hefei ; cheng, hui-ming] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; du, jh (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china. ; jhdu@imr.ac.cn
关键词Organic Solar-cells Poly(Styrenesulfonate) Films Pedot-pss Electrodes Polymer Poly(3,4-ethylenedioxythiophene) Enhancement
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语种英语
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/73311
专题中国科学院金属研究所
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GB/T 7714
W. B. Liu,J. H. Du,L. P. Ma,et al. Fabrication of a large-area, flexible and color-neutral single-wall carbon nanotube:sodium dodecylbenzene sulfonate/poly-(3,4-ethylenedioxythiophene): poly(4-styrenesulfonate) transparent conductive film having a new conduction mechanism[J]. Carbon,2014,80:112-119.
APA W. B. Liu,J. H. Du,L. P. Ma,H. F. Zhu,&H. M. Cheng.(2014).Fabrication of a large-area, flexible and color-neutral single-wall carbon nanotube:sodium dodecylbenzene sulfonate/poly-(3,4-ethylenedioxythiophene): poly(4-styrenesulfonate) transparent conductive film having a new conduction mechanism.Carbon,80,112-119.
MLA W. B. Liu,et al."Fabrication of a large-area, flexible and color-neutral single-wall carbon nanotube:sodium dodecylbenzene sulfonate/poly-(3,4-ethylenedioxythiophene): poly(4-styrenesulfonate) transparent conductive film having a new conduction mechanism".Carbon 80(2014):112-119.
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