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PdO loaded TiO2 hollow sphere composite photocatalyst with a high photocatalytic disinfection efficiency on bacteria
Y. Liu; J. T. Zhang; W. Z. Sun; S. A. Gao; J. K. Shang
2014
Source PublicationChemical Engineering Journal
ISSN1385-8947
Volume249Pages:63-71
AbstractPdO loaded TiO2 hollow spheres were synthesized via first reducing Pd2+ to Pd in ethanol onto TiO2 hollow spheres by refluxing and then oxidizing Pd to PdO through calcination in air. PdO nanoparticles were distributed relatively uniformly both on the surface and in the shell/interior of these TiO2 hollow spheres, to act as potential electron/hole pair separation centers. These PdO loaded TiO2 hollow spheres demonstrated a superior photocatalytic disinfection performance on Eschetichia coil bacteria, compared with the unloaded samples or P25 TiO2 nanoparticles. Their largely enhanced photocatalytic disinfection performance could be attributed to both their unique hollow structure and the electron trapping capability of loaded PdO nanoparticles. Samples with a series of PdO loading ratios were synthesized and tested to determine the optimum PdO loading ratio, which was found to be similar to 0.4 wt.%. Below the optimum PdO loading, the photocatalytic disinfection performance increased with the increase of PdO loading ratio, while further increase of the PdO loading over 0.4% resulted in a deleterious influence on the PdO enhancement effect. The photocatalytic performance differences between Pd and PdO modified samples were also investigated. Samples with 0.4% PdO modification demonstrated a better photocatalytic disinfection effect on E. coli bacteria than samples with 0.4% Pd modification, which could be attributed to their different work functions. (C) 2014 Elsevier B.V. All rights reserved.
description.department[liu, yang ; zhang, jingtao ; sun, wuzhu ; gao, shian ; shang, jian ku] chinese acad sci, inst met res, shenyang natl lab mat sci, environm funct mat div, shenyang 110016, peoples r china. [shang, jian ku] univ illinois, dept mat sci & engn, urbana, il 61801 usa. ; liu, y (reprint author), 72 wenhua rd, shenyang 110016, liaoning provin, peoples r china. ; qili@imr.ac.cn
KeywordTio2 Hollow Sphere Pdo Nanoparticles Electron/hole Separation Photocatalytic Disinfection Bacteria Doped Titanium-oxide One-pot Synthesis Fabrication Nanoparticles Oxidation Nanocomposites Nanomaterials Nanospheres Performance Catalysts
URL查看原文
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/73316
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
Y. Liu,J. T. Zhang,W. Z. Sun,et al. PdO loaded TiO2 hollow sphere composite photocatalyst with a high photocatalytic disinfection efficiency on bacteria[J]. Chemical Engineering Journal,2014,249:63-71.
APA Y. Liu,J. T. Zhang,W. Z. Sun,S. A. Gao,&J. K. Shang.(2014).PdO loaded TiO2 hollow sphere composite photocatalyst with a high photocatalytic disinfection efficiency on bacteria.Chemical Engineering Journal,249,63-71.
MLA Y. Liu,et al."PdO loaded TiO2 hollow sphere composite photocatalyst with a high photocatalytic disinfection efficiency on bacteria".Chemical Engineering Journal 249(2014):63-71.
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