|Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage|
|J. W. Ren; N. M. Musyoka; H. W. Langmi; B. C. North; M. Mathe; X. D. Kang
|Source Publication||International Journal of Hydrogen Energy
|Abstract||The fabrication of core-shell nanocrystals by incorporating microporous UiO-66 into mesoporous MIL-101 is reported. The growth of the core-shell MIL-101@UiO-66 nanocrystals was observed and supported by TEM and PXRD. The accessible pore volumes of the individual metal-organic framework (MOF) components and the core-shell hybrid crystals were also characterized. The hydrogen storage capacity exhibited by the resulting core -shell nanocrystals was 26% and 60% higher than those of pure phase MIL-101 and UiO-66, respectively. Finally, the fabricated core-shell MIL-101@UiO-66 structure exhibited a high degree of moisture tolerance. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.|
; musyoka, nicholas m.
; langmi, henrietta w.
; north, brian c.
; mathe, mkhulu] csir, hysa infrastruct ctr competence mat sci & mfg, za-0001 pretoria, south africa. [kang, xiangdong] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china.
; ren, jw (reprint author), csir, hysa infrastruct ctr competence mat sci & mfg, pob 395, za-0001 pretoria, south africa.
J. W. Ren,N. M. Musyoka,H. W. Langmi,et al. Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage[J]. International Journal of Hydrogen Energy,2014,39(27):14912-14917.
J. W. Ren,N. M. Musyoka,H. W. Langmi,B. C. North,M. Mathe,&X. D. Kang.(2014).Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage.International Journal of Hydrogen Energy,39(27),14912-14917.
J. W. Ren,et al."Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage".International Journal of Hydrogen Energy 39.27(2014):14912-14917.
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