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Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage
J. W. Ren; N. M. Musyoka; H. W. Langmi; B. C. North; M. Mathe; X. D. Kang
2014
Source PublicationInternational Journal of Hydrogen Energy
ISSN0360-3199
Volume39Issue:27Pages:14912-14917
AbstractThe fabrication of core-shell nanocrystals by incorporating microporous UiO-66 into mesoporous MIL-101 is reported. The growth of the core-shell MIL-101@UiO-66 nanocrystals was observed and supported by TEM and PXRD. The accessible pore volumes of the individual metal-organic framework (MOF) components and the core-shell hybrid crystals were also characterized. The hydrogen storage capacity exhibited by the resulting core -shell nanocrystals was 26% and 60% higher than those of pure phase MIL-101 and UiO-66, respectively. Finally, the fabricated core-shell MIL-101@UiO-66 structure exhibited a high degree of moisture tolerance. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
description.department[ren, jianwei ; musyoka, nicholas m. ; langmi, henrietta w. ; north, brian c. ; mathe, mkhulu] csir, hysa infrastruct ctr competence mat sci & mfg, za-0001 pretoria, south africa. [kang, xiangdong] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; ren, jw (reprint author), csir, hysa infrastruct ctr competence mat sci & mfg, pob 395, za-0001 pretoria, south africa. ; jren@csir.co.za
KeywordCore-shell Mofs Mil-101 Uio-66 Moisture Tolerance Hydrogen Storage Metal-organic Frameworks Determining Surface-areas Bet Method Mof
URL查看原文
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/73360
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
J. W. Ren,N. M. Musyoka,H. W. Langmi,et al. Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage[J]. International Journal of Hydrogen Energy,2014,39(27):14912-14917.
APA J. W. Ren,N. M. Musyoka,H. W. Langmi,B. C. North,M. Mathe,&X. D. Kang.(2014).Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage.International Journal of Hydrogen Energy,39(27),14912-14917.
MLA J. W. Ren,et al."Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage".International Journal of Hydrogen Energy 39.27(2014):14912-14917.
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