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The effect of fluoride ions on the corrosion behavior of pure titanium in 0.05 M sulfuric acid
Z. B. Wang; H. X. Hu; C. B. Liu; Y. G. Zheng
2014
Source PublicationElectrochimica Acta
ISSN0013-4686
Volume135Pages:526-535
AbstractThe corrosion behavior of pure titanium was investigated in 0.05 M H2SO4 solution with fluoride ions using various electrochemical techniques, such as open circuit potential (OCP), potentiodynamic polarization, electrochemical impedance measurements (EIS) and surface analyses via X-ray photoelectron spectroscopy (XPS). The results showed that titanium exhibited spontaneous passivation behavior in solutions with 0 M and 0.0005 M fluoride ions, compared with the active-passive behavior with 0.002 M similar to 0.005 M. A critical value of the fluoride concentration was defined between 0.0005 M and 0.002 M. Multiple corrosion potentials were found under the conditions with fluoride ions higher than 0.002 M. The fluoride ion accelerated the corrosion of titanium via changing the structure of the film formed at OCP and destroying the protectiveness of the film, while it had few effects on cathodic hydrogen evolution reaction and passivation process at OCP. A corrosion mechanism associated with the fluoride ion was proposed. The corrosion behavior was well interpreted using the proposed mechanism and a criteria for the critical value of the fluoride concentration was also proposed. (C) 2014 Elsevier Ltd. All rights reserved.
description.department[wang, z. b. ; hu, h. x. ; zheng, y. g.] chinese acad sci, inst met res, key lab nucl mat & safety assessment, shenyang 110016, peoples r china. [liu, c. b.] huadian zhengzhou mech design inst co ltd, ctr wear & corros resistant mat, zhengzhou 450015, peoples r china. ; zheng, yg (reprint author), chinese acad sci, inst met res, key lab nucl mat & safety assessment, 62 wencui rd, shenyang 110016, peoples r china. ; ygzheng@imr.ac.cn
KeywordTitanium Fluoride Ion Film Critical Value Multiple Corrosion Potentials Electrochemical Impedance Spectroscopy Passive Oxide-film Hydrofluoric-acid Dissolved-oxygen Xps Analysis Alloys Ti Dissolution Chloride Surface
URL查看原文
Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/73434
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
Z. B. Wang,H. X. Hu,C. B. Liu,et al. The effect of fluoride ions on the corrosion behavior of pure titanium in 0.05 M sulfuric acid[J]. Electrochimica Acta,2014,135:526-535.
APA Z. B. Wang,H. X. Hu,C. B. Liu,&Y. G. Zheng.(2014).The effect of fluoride ions on the corrosion behavior of pure titanium in 0.05 M sulfuric acid.Electrochimica Acta,135,526-535.
MLA Z. B. Wang,et al."The effect of fluoride ions on the corrosion behavior of pure titanium in 0.05 M sulfuric acid".Electrochimica Acta 135(2014):526-535.
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