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Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis
S. C. Wu; G. D. Wen; X. M. Liu; B. W. Zhong; D. S. Su
2014
Source PublicationChemcatchem
ISSN1867-3880
Volume6Issue:6Pages:1558-1561
AbstractThe role of different oxygen functional groups on a carbon catalyst was studied in the reduction of nitrobenzene by using a series of model molecules. The carbonyl and hydroxyl groups played important roles, which may be ascribed to their ability to activate hydrazine. In comparison, the ester, ether, and lactone groups seemed to be inactive, whereas the carboxylic group had a negative effect. The reaction occurred most likely through a direct route, during which nitrosobenzene may be converted directly into aniline.
description.department[wu, shuchang ; wen, guodong ; zhong, bingwei ; su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. [wu, shuchang] chinese acad sci, grad univ, beijing 100049, peoples r china. [liu, xiumei] chinese acad sci, dalian inst chem phys, state key lab catalysis, dalian 116023, peoples r china. ; su, ds (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china. ; dssu@imr.ac.cn
KeywordActive Sites Carbocatalysis Model Catalyst Reaction Mechanisms Reduction Oxidative Dehydrogenation Graphene Oxide Carbon Nanotubes Nitro-compounds Aerobic Oxidation Graphite Oxide N-butane Chemistry Efficient
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Language英语
Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/73446
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
S. C. Wu,G. D. Wen,X. M. Liu,et al. Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis[J]. Chemcatchem,2014,6(6):1558-1561.
APA S. C. Wu,G. D. Wen,X. M. Liu,B. W. Zhong,&D. S. Su.(2014).Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis.Chemcatchem,6(6),1558-1561.
MLA S. C. Wu,et al."Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis".Chemcatchem 6.6(2014):1558-1561.
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