Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis

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	Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis
	S. C. Wu; G. D. Wen; X. M. Liu; B. W. Zhong; D. S. Su
	2014
Source Publication	Chemcatchem
ISSN	1867-3880
Volume	6 Issue:6 Pages:1558-1561
Abstract	The role of different oxygen functional groups on a carbon catalyst was studied in the reduction of nitrobenzene by using a series of model molecules. The carbonyl and hydroxyl groups played important roles, which may be ascribed to their ability to activate hydrazine. In comparison, the ester, ether, and lactone groups seemed to be inactive, whereas the carboxylic group had a negative effect. The reaction occurred most likely through a direct route, during which nitrosobenzene may be converted directly into aniline.
description.department	[wu, shuchang ; wen, guodong ; zhong, bingwei ; su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. [wu, shuchang] chinese acad sci, grad univ, beijing 100049, peoples r china. [liu, xiumei] chinese acad sci, dalian inst chem phys, state key lab catalysis, dalian 116023, peoples r china. ; su, ds (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, 72 wenhua rd, shenyang 110016, peoples r china. ; dssu@imr.ac.cn
Keyword	Active Sites Carbocatalysis Model Catalyst Reaction Mechanisms Reduction Oxidative Dehydrogenation Graphene Oxide Carbon Nanotubes Nitro-compounds Aerobic Oxidation Graphite Oxide N-butane Chemistry Efficient
URL	查看原文
Language	英语
Document Type	期刊论文
Identifier	http://ir.imr.ac.cn/handle/321006/73446
Collection	中国科学院金属研究所
Recommended Citation GB/T 7714	S. C. Wu,G. D. Wen,X. M. Liu,et al. Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis[J]. Chemcatchem,2014,6(6):1558-1561.
APA	S. C. Wu,G. D. Wen,X. M. Liu,B. W. Zhong,&D. S. Su.(2014).Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis.Chemcatchem,6(6),1558-1561.
MLA	S. C. Wu,et al."Model Molecules with Oxygenated Groups Catalyze the Reduction of Nitrobenzene: Insight into Carbocatalysis".Chemcatchem 6.6(2014):1558-1561.

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