Heterogenization of homogenous reaction system on carbon surface with ionic liquid as mediator

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	Heterogenization of homogenous reaction system on carbon surface with ionic liquid as mediator
	Y. X.; Zhang Ding, B. S.; Gupta, N.; Su, D. S.
	2015
发表期刊	Green Chemistry
ISSN	1463-9262
卷号	17 期号:2 页码:1107-1112
摘要	A new concept of ionic liquid (IL) mono-dispersing catalyst on nanocarbon surface is presented. The liquid mixture of IL and model catalyst (1-octyl-3-methyl imidazolium phosphotungstate, OPW) on carbon nanotube is in a solid state which can be easily characterized and give a fundamental understanding of the interaction between the catalyst and the IL. The condensed IL is found to weaken the W=O bond of a catalyst that favours its interaction with an oxidizing agent that exhibited a reaction rate of 176 times to the performance of a single OPW during the oxidation of dibenzothiophene. Due to the hetero-genization of this system, the catalyst can be easily recycled by a simple gravity separation.
部门归属	[ding, yuxiao ; zhang, bingsen ; gupta, neeraj ; su, dang sheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; ding, yx (reprint author), chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china. ; dssu@imr.ac.cn
关键词	Hydrogen-bond Nanotubes Catalysis Solvents Oxidation Future
URL	查看原文
语种	英语
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/73785
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	Y. X.,Zhang Ding, B. S.,Gupta, N.,et al. Heterogenization of homogenous reaction system on carbon surface with ionic liquid as mediator[J]. Green Chemistry,2015,17(2):1107-1112.
APA	Y. X.,Zhang Ding, B. S.,Gupta, N.,&Su, D. S..(2015).Heterogenization of homogenous reaction system on carbon surface with ionic liquid as mediator.Green Chemistry,17(2),1107-1112.
MLA	Y. X.,et al."Heterogenization of homogenous reaction system on carbon surface with ionic liquid as mediator".Green Chemistry 17.2(2015):1107-1112.