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THE INHIBITORY EFFECT OF SOME BIPYRIDINE DERIVATIVES ON THE CORROSION BEHAVIOR OF N80 CARBON STEEL IN SULPHURIC ACID SOLUTIONS
X.; Okafor Liu, P. C.; Jiang, B.; Hu, H. X.; Zheng, Y. G.
2015
Source PublicationSurface Review and Letters
ISSN0218-625X
Volume22Issue:1
AbstractThe corrosion inhibition characteristics of 2,2'-bipyridine (BIPY) and 2,2'-bipyridine-3,3'-dicarboxylic acid (BIDA), on carbon steel in sulphuric acid solutions was studied using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques at 20 degrees C, 30 degrees C and 40 degrees C. The results indicate that the organic compounds inhibit the corrosion of mild steel in H2SO4 solutions and the extent of inhibition increases with inhibitor concentration and decreases with temperature. A mixed-inhibition mechanism is proposed for the inhibitive effects of the compounds. The order of inhibition efficiency obtained was BIDA>BIPY. There is a good correlation between the quantum chemical parameters and experimentally determined inhibition efficiency of the inhibitors. The adsorption characteristics of the inhibitor were approximated by Temkin isotherm. Morphological study of the carbon steel electrode surface was undertaken by scanning electron microscope (SEM) and the interfacial species formed on the surface in the presence of inhibitors analyzed by Infrared spectroscopy.
description.department[liu, xia] shenyang univ chem technol, dept appl chem, shenyang, peoples r china. [okafor, peter c.] univ calabar, dept pure & appl chem, corros & electrochem res grp, calabar, nigeria. [okafor, peter c. ; jiang, bin ; hu, hongxiang ; zheng, yugui] chinese acad sci, inst met res, state key lab corros & protect, shenyang 110016, peoples r china. ; liu, x (reprint author), shenyang univ chem technol, dept appl chem, shenyang, peoples r china. ; laura-lx@163.com
KeywordCorrosion Inhibitor Bipyridine Derivative Carbon Steel Infrared Spectroscopy Cold-rolled Steel Mild-steel Hydrochloric-acid Synergistic Inhibition Impedance Spectroscopy Dioxide Corrosion H2so4 Solutions Iron Corrosion Hcl Solution Adsorption
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Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/73870
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
X.,Okafor Liu, P. C.,Jiang, B.,et al. THE INHIBITORY EFFECT OF SOME BIPYRIDINE DERIVATIVES ON THE CORROSION BEHAVIOR OF N80 CARBON STEEL IN SULPHURIC ACID SOLUTIONS[J]. Surface Review and Letters,2015,22(1).
APA X.,Okafor Liu, P. C.,Jiang, B.,Hu, H. X.,&Zheng, Y. G..(2015).THE INHIBITORY EFFECT OF SOME BIPYRIDINE DERIVATIVES ON THE CORROSION BEHAVIOR OF N80 CARBON STEEL IN SULPHURIC ACID SOLUTIONS.Surface Review and Letters,22(1).
MLA X.,et al."THE INHIBITORY EFFECT OF SOME BIPYRIDINE DERIVATIVES ON THE CORROSION BEHAVIOR OF N80 CARBON STEEL IN SULPHURIC ACID SOLUTIONS".Surface Review and Letters 22.1(2015).
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