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Thermochemistry of some binary lead and transition metal compounds by high temperature direct synthesis calorimetry
S. V.; Nash Meschel, P.; Chen, X. Q.; Wei, P.
2015
Source PublicationJournal of Alloys and Compounds
ISSN0925-8388
Volume633Pages:183-187
AbstractThe standard enthalpies of formation of some binary lead and transition metal compounds have been measured by high temperature direct synthesis calorimetry. The reported results are: Pb3Sc5(-61.3 +/- 2.9); PbTi4(-16.6 +/- 2.4); Pb3Y5(-64.8 +/- 3.6); Pb3Zr5(-50.6 +/- 3.1); PbNb3(-10.4 +/- 3.4); PbRh(-16.5 +/- 3.3); PbPd3(-29.6 +/- 3.1); PbPt(-34.7 +/- 3.3) kJ/mole of atoms. We will compare our results with previously published measurements. We will also compare the experimental measurements with enthalpies of formation of transition metal compounds with elements in the same vertical column in the periodic table. We will compare our measurements with predicted values on the basis of the semi empirical model of Miedema and coworkers and with ab initio values when available. (C) 2015 Elsevier B.V. All rights reserved.
description.department[meschel, s. v. ; nash, p.] iit, thermal proc technol ctr, chicago, il 60615 usa. [meschel, s. v.] gordon ctr integrated sci, chicago, il 60637 usa. [chen, x. q. ; wei, p.] acad sinica, inst met res, shenyang natl lab mat sci, mat proc modeling div, shenyang 110015, peoples r china. ; meschel, sv (reprint author), iit, thermal proc technol ctr, 10 w 32nd st, chicago, il 60615 usa. ; meschel@jfi.uchicago.edu
KeywordThermodynamics Enthalpies Of Formation Augmented-wave Method Standard Enthalpies Pb Alloys Reactors Elements Systems Zr5pb3
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Document Type期刊论文
Identifierhttp://ir.imr.ac.cn/handle/321006/73889
Collection中国科学院金属研究所
Recommended Citation
GB/T 7714
S. V.,Nash Meschel, P.,Chen, X. Q.,et al. Thermochemistry of some binary lead and transition metal compounds by high temperature direct synthesis calorimetry[J]. Journal of Alloys and Compounds,2015,633:183-187.
APA S. V.,Nash Meschel, P.,Chen, X. Q.,&Wei, P..(2015).Thermochemistry of some binary lead and transition metal compounds by high temperature direct synthesis calorimetry.Journal of Alloys and Compounds,633,183-187.
MLA S. V.,et al."Thermochemistry of some binary lead and transition metal compounds by high temperature direct synthesis calorimetry".Journal of Alloys and Compounds 633(2015):183-187.
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