| A novel preparation of Zr-Si intermetallics by electrochemical reduction of ZrSiO4 in molten salts | |
| Liu, Hongxia; Cai, Yanqing; Xu, Qian; Song, Qiushi; Liu, Huijun; qianxu201@mail.neu.edu.cn | |
| 2015 | |
| Source Publication | NEW JOURNAL OF CHEMISTRY
 |
| ISSN | 1144-0546 |
| Volume | 39Issue:12Pages:9969-9975 |
| Abstract | A method of controllably preparing Zr-Si intermetallics by the electrochemical reduction of ZrSiO4 and ZrSiO4-SiO2 mixed powders in molten CaCl2-NaCl at 800 degrees C is developed. The final product composition can be controlled by adjusting the molar ratio of Si to Zr in the starting material, and ZrSi, ZrSi2 and their mixture were obtained by this process. The reduction pathway of ZrSiO4 and SiO2 to Zr-Si intermetallics involves several calcium-containing intermediate phases, such as CaSiO3, Ca-2 SiO4, and calcia-stabilized zirconia (CSZ). |
| description.department | [liu, hongxia ; cai, yanqing ; song, qiushi] northeastern univ, sch mat sci & met, shenyang 110004, peoples r china ; [liu, hongxia] inner mongolia univ technol, sch mat sci & engn, hohhot 010051, peoples r china ; [xu, qian] shanghai univ, state key lab adv special steel, shanghai 200072, peoples r china ; [liu, huijun] chinese acad sci, inst met res, lab corros & protect, shenyang 110016, peoples r china |
| Funding Organization | National Natural Science Foundation of China [51174055] |
| Indexed By | sci |
| Language | 英语 |
| WOS ID | WOS:000365222000109 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.imr.ac.cn/handle/321006/74599 |
| Collection | 中国科学院金属研究所 |
| Corresponding Author | qianxu201@mail.neu.edu.cn |
| Recommended Citation GB/T 7714 | Liu, Hongxia,Cai, Yanqing,Xu, Qian,et al. A novel preparation of Zr-Si intermetallics by electrochemical reduction of ZrSiO4 in molten salts[J]. NEW JOURNAL OF CHEMISTRY,2015,39(12):9969-9975. |
| APA | Liu, Hongxia,Cai, Yanqing,Xu, Qian,Song, Qiushi,Liu, Huijun,&qianxu201@mail.neu.edu.cn.(2015).A novel preparation of Zr-Si intermetallics by electrochemical reduction of ZrSiO4 in molten salts.NEW JOURNAL OF CHEMISTRY,39(12),9969-9975. |
| MLA | Liu, Hongxia,et al."A novel preparation of Zr-Si intermetallics by electrochemical reduction of ZrSiO4 in molten salts".NEW JOURNAL OF CHEMISTRY 39.12(2015):9969-9975. |
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