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Anisotropic electronic conduction in stacked two-dimensional titanium carbide
Hu, Tao; Zhang, Hui; Wang, Jiemin; Li, Zhaojin; Hu, Minmin; Tan, Jun; Hou, Pengxiang; Li, Feng; Wang, Xiaohui; wang@imr.ac.cn
2015
发表期刊SCIENTIFIC REPORTS
ISSN2045-2322
卷号5页码:-
摘要Stacked two-dimensional titanium carbide is an emerging conductive material for electrochemical energy storage which requires an understanding of the intrinsic electronic conduction. Here we report the electronic conduction properties of stacked Ti3C2T2 (T = OH, O, F) with two distinct stacking sequences (Bernal and simple hexagonal). On the basis of first-principles calculations and energy band theory analysis, both stacking sequences give rise to metallic conduction with Ti 3d electrons contributing most to the conduction. The conduction is also significantly anisotropic due to the fact that the effective masses of carriers including electrons and holes are remarkably direction-dependent. Such an anisotropic electronic conduction is evidenced by the I-V curves of an individual Ti3C2T2 particulate, which demonstrates that the in-plane electrical conduction is at least one order of magnitude higher than that vertical to the basal plane.
部门归属[hu, tao ; zhang, hui ; wang, jiemin ; li, zhaojin ; hu, minmin ; tan, jun ; hou, pengxiang ; li, feng ; wang, xiaohui] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china ; [hu, tao ; zhang, hui ; li, zhaojin ; hu, minmin] univ chinese acad sci, beijing 100049, peoples r china
资助者Chinese Academy of Sciences (CAS); Shenyang National Laboratory for Materials Science, Institute of Metal Research, CAS
收录类别sci
语种英语
WOS记录号WOS:000364303200001
引用统计
被引频次:126[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/74630
专题中国科学院金属研究所
通讯作者wang@imr.ac.cn
推荐引用方式
GB/T 7714
Hu, Tao,Zhang, Hui,Wang, Jiemin,et al. Anisotropic electronic conduction in stacked two-dimensional titanium carbide[J]. SCIENTIFIC REPORTS,2015,5:-.
APA Hu, Tao.,Zhang, Hui.,Wang, Jiemin.,Li, Zhaojin.,Hu, Minmin.,...&wang@imr.ac.cn.(2015).Anisotropic electronic conduction in stacked two-dimensional titanium carbide.SCIENTIFIC REPORTS,5,-.
MLA Hu, Tao,et al."Anisotropic electronic conduction in stacked two-dimensional titanium carbide".SCIENTIFIC REPORTS 5(2015):-.
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