Anisotropic electronic conduction in stacked two-dimensional titanium carbide | |
Hu, Tao; Zhang, Hui; Wang, Jiemin; Li, Zhaojin; Hu, Minmin; Tan, Jun; Hou, Pengxiang; Li, Feng; Wang, Xiaohui; wang@imr.ac.cn | |
2015 | |
发表期刊 | SCIENTIFIC REPORTS
![]() |
ISSN | 2045-2322 |
卷号 | 5页码:- |
摘要 | Stacked two-dimensional titanium carbide is an emerging conductive material for electrochemical energy storage which requires an understanding of the intrinsic electronic conduction. Here we report the electronic conduction properties of stacked Ti3C2T2 (T = OH, O, F) with two distinct stacking sequences (Bernal and simple hexagonal). On the basis of first-principles calculations and energy band theory analysis, both stacking sequences give rise to metallic conduction with Ti 3d electrons contributing most to the conduction. The conduction is also significantly anisotropic due to the fact that the effective masses of carriers including electrons and holes are remarkably direction-dependent. Such an anisotropic electronic conduction is evidenced by the I-V curves of an individual Ti3C2T2 particulate, which demonstrates that the in-plane electrical conduction is at least one order of magnitude higher than that vertical to the basal plane. |
部门归属 | [hu, tao ; zhang, hui ; wang, jiemin ; li, zhaojin ; hu, minmin ; tan, jun ; hou, pengxiang ; li, feng ; wang, xiaohui] chinese acad sci, shenyang natl lab mat sci, inst met res, shenyang 110016, peoples r china ; [hu, tao ; zhang, hui ; li, zhaojin ; hu, minmin] univ chinese acad sci, beijing 100049, peoples r china |
资助者 | Chinese Academy of Sciences (CAS); Shenyang National Laboratory for Materials Science, Institute of Metal Research, CAS |
收录类别 | sci |
语种 | 英语 |
WOS记录号 | WOS:000364303200001 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/74630 |
专题 | 中国科学院金属研究所 |
通讯作者 | wang@imr.ac.cn |
推荐引用方式 GB/T 7714 | Hu, Tao,Zhang, Hui,Wang, Jiemin,et al. Anisotropic electronic conduction in stacked two-dimensional titanium carbide[J]. SCIENTIFIC REPORTS,2015,5:-. |
APA | Hu, Tao.,Zhang, Hui.,Wang, Jiemin.,Li, Zhaojin.,Hu, Minmin.,...&wang@imr.ac.cn.(2015).Anisotropic electronic conduction in stacked two-dimensional titanium carbide.SCIENTIFIC REPORTS,5,-. |
MLA | Hu, Tao,et al."Anisotropic electronic conduction in stacked two-dimensional titanium carbide".SCIENTIFIC REPORTS 5(2015):-. |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论